1,4-二碘五环[4.2.0.02,5.03,8.04,7]辛烷合成路线 （共 9 条）
反应条件
in tetrahydrofuran; pentane T=-78°C; effect of substrates addition order; var. alkyllithium and aryllithium; other 4-haloiodocubanes; Product distributionMechanism;
参考文献
Eaton; Tsanaktsidis
Journal of the American Chemical Society, 1990 , vol. 112, # 2 p. 876 - 878
反应条件
1,3-Diiodo-5,5-dimethyl-2,4-imidazolidinedione in 1,2-dichloro-ethane
2 h; RefluxIrradiation; Product distribution / selectivity;
参考文献
TECHNION RandD FOUNDATION LTD.; NISNEVICH, Gennady; GANDELMAN, Mark; KULBITSKI, Kseniya
Patent: WO2011/154953 A1, 2011 ;
Location in patent: Page/Page column 28-30 ;
反应条件
4-(N,N-dimethlyamino)pyridine; 1-iodo-2,2,2-trifluoroethane; Fonderma in benzene
2.5 h; HeatingIrradiation;
参考文献
Eaton, Philip E.; Li, Jianchang; Upadhyaya, Subhash P.
Journal of Organic Chemistry, 1995 , vol. 60, # 4 p. 966 - 968
反应条件
sodium hydroxide; chloroform in dichloromethane
T=25°C; 192 h; Title compound not separated from byproducts.;
参考文献
Fokin; Lauenstein; Gunchenko; Schreiner
Journal of the American Chemical Society, 2001 , vol. 123, # 9 p. 1842 - 1847
反应条件
1,3-Diiodo-5,5-dimethyl-2,4-imidazolidinedione in 1,2-dichloro-ethane
2 h; IrradiationInert atmosphereReflux;
参考文献
Kulbitski, Kseniya; Nisnevich, Gennady; Gandelman, Mark
Advanced Synthesis and Catalysis, 2011 , vol. 353, # 9 p. 1438 - 1442
反应条件
bromine; aluminium in dichloromethane
T=80°C; 0.5 h;
参考文献
Honegger, Evi; Heilbronner, Edgar; Urbanek, Thomas; Martin, Hans-Dieter
Helvetica Chimica Acta, 1985 , vol. 68, p. 23 - 38
反应条件
t-BuOI in tetrachloromethane; 1,2,2-trifluoro-trichloroethane
Irradiation; Further byproducts given;
参考文献
Reddy; Maggini; Tsanaktsidis; Ecton
Tetrahedron Letters, 1990 , vol. 31, # 6 p. 805 - 806
反应条件
t-BuOI in 1,2,2-trifluoro-trichloroethane
24 h; Irradiation;
参考文献
Reddy; Maggini; Tsanaktsidis; Ecton
Tetrahedron Letters, 1990 , vol. 31, # 6 p. 805 - 806
反应条件
1: With ethylmagnesium bromide in tetrahydrofuran
T=-78°C; Inert atmosphere;
2: With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; 0.0833333 h; Inert atmosphere;
3: With methanol; sodium methylate in tetrahydrofuran; hexane
1 h; Inert atmosphereReflux;
参考文献
Griffiths, Justin R.; Tsanaktsidis, John; Savage, G. Paul; Priefer, Ronny
Thermochimica Acta, 2010 , vol. 499, # 1-2 p. 15 - 20
