tris(dibenzylideneacetone)dipalladium (0) in tetrahydrofuran T=50°C; 3 h;

1: (Ra)-BINOL-(O-)2P-N-c-C12-N-(R)-(2-MeO-PhCH-Me); [(COD)IrCl]2; CsF / ZnF2; propylamine / tetrahydrofuran; bis-(2-methoxy-ethyl) ether / 18 h / 50 °C 2: 74 mg / [(PPh3)3RhCl]; H2 / tetrahydrofuran / 9 h / 20 °C / 750.06 Torr View Scheme

sodium hydride; [Cp*Ru(CNCH3)3]+PF6- in N,N-dimethyl-formamide

[Cp*Ru(CNCH3)3]+PF6- in acetone T=20°C;

N,O-bis-(trimethylsilyl)-acetamide; dichloro(cycloocta-1,5-diene)palladium(II); potassium acetate; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene in tetrahydrofuran T=20°C; 12 h; Inert atmosphere;