1: p-methoxy-phenylmagnesium chloride With zinc(II) chloride in tetrahydrofuran
T=20°C; 0.333333 h;
2: ortho-chlorotoluene With Pd0(tris(tert-butyl)phosphine)2 in tetrahydrofuran; 1-methyl-pyrrolidin-2-one
T=100°C; Negishi reaction; 24 h; Further stages.;
参考文献
Dai; Fu
Journal of the American Chemical Society, 2001 , vol. 123, # 12 p. 2719 - 2724
1: triallyl(4-methoxyphenyl)silane With tetrabutyl ammonium fluoride in tetrahydrofuran; water
T=20°C; 1 h;
2: ortho-chlorotoluene With 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl; bis(η3-allyl-μ-chloropalladium(II)) in tetrahydrofuran; water
T=80°C; 4 h;
Pd0(tris(tert-butyl)phosphine)2 in toluene
T=90°C; Inert atmosphere;
参考文献
Denmark, Scott E.; Smith, Russell C.; Chang, Wen-Tau T.; Muhuhi, Joseck M.
Journal of the American Chemical Society, 2009 , vol. 131, # 8 p. 3104 - 3118
