1: With palladium diacetate; tetra-n-butylammonium acetate; potassium carbonate; potassium chloride in N,N-dimethyl-formamide T=90°C; 6 h; 2: With hydrogenchloride; water in N,N-dimethyl-formamide
CO in hexane loading an autoclave cup with Fe-compound in hexane and CO (500 psig, 25°C), heating (160°C, 700 psig, 19 h); cooling, transferring of soln. to a Schlenk flask (N2), GC and IR;
参考文献
Ogilvy; Draganjac; Rauchfuss; Wilson
1988 , vol. 7, # 5 p. 1171 - 1177
flash vac. pyrolysis in a Pyrex tube connected with a cold trap (E-5 Torr, 285-315°C); coating of the hot zone by Fe, rinsing of trap with acetone, GC;
