(E)-3-苯基-2-丁烯酸乙酯合成路线 （共 15 条）
反应条件
1: ethanol; nickel catalyst / Hydrogenation 2: aq. NaOH solution View Scheme
参考文献
Rupe; van Walraven
Helvetica Chimica Acta, 1930 , vol. 13, p. 361,375
反应条件
1: potassium hydroxide / ethanol; water / 5 h / 20 °C 2: [bis(acetoxy)iodo]benzene; iodine / dichloromethane / 2 h / 20 °C / |Irradiation; |Green chemistry View Scheme
参考文献
RSC Advances, , vol. 3, # 13 p. 4311 - 4320
反应条件
1: NaOH / ethanol; H2O / Heating 2: H2 / Ru(OCOCH3)2<(S)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl> / methanol / 7 h / 76000 Torr / Ambient temperature View Scheme
参考文献
Uemura, Toshitsugi; Zhang, Xiaoyoung; Matsumura, Kazuhiko; Sayo, Noboru; Kumobayashi, Hidenori; Ohta, Tetsuo; Nozaki, Kyoko; Takaya, Hidemasa
Journal of Organic Chemistry, 1996 , vol. 61, # 16 p. 5510 - 5516
反应条件
1,4-dioxane; selenium(IV) oxide
参考文献
Torrey; Kuck; Elderfield
Journal of Organic Chemistry, 1941 , vol. 6, p. 289,294
反应条件
caesium carbonate; [(t-Bu)3PH]BF4; 3,4,5-trimethoxyphenylboronic acid; tris(dibenzylideneacetone)dipalladium (0) in 1,4-dioxane Heating;
参考文献
Simard-Mercier, Julie; Jiang, Jojo Liu; Ho, Michael L.; Flynn, Alison B.; Ogilvie, William W.
Journal of Organic Chemistry, 2008 , vol. 73, # 15 p. 5899 - 5906
反应条件
1: 98 percent / i-PrMgCl / tetrahydrofuran / 0.5 h / -5 °C 2: tetrahydrofuran 3: H2 / Pd/C View Scheme
参考文献
Wang, Duo-Sheng; Wang, Da-Wei; Zhou, Yong-Gui
Synlett, 2011 , # 7 p. 947 - 950
反应条件
1: i-PrMgCl / tetrahydrofuran / 0.5 h / -5 °C
2: tetrahydrofuran
3: H2 / Pd/C
View Scheme
参考文献
Wang, Duo-Sheng; Wang, Da-Wei; Zhou, Yong-Gui
Synlett, 2011 , # 7 p. 947 - 950
反应条件
lithium diisopropyl amide in tetrahydrofuran
1.) -78 deg C, 1 h, 2.) -78 deg C -> room temperature, 1 h;
参考文献
Smith,A.B.; Toder,B.H.; Branca,S.J.
Journal of the American Chemical Society, 1981 , vol. 103, p. 1996
反应条件
1: 98 percent / i-PrMgCl / tetrahydrofuran / 0.5 h / -5 °C
2: tetrahydrofuran
View Scheme
参考文献
Wang, Duo-Sheng; Wang, Da-Wei; Zhou, Yong-Gui
Synlett, 2011 , # 7 p. 947 - 950
反应条件
1: NaOH / ethanol; H2O / Heating
2: H2 / <RuI((R)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl)(p-cymene)>I / methanol / 25 h / 3040 Torr / Ambient temperature
View Scheme
参考文献
Uemura, Toshitsugi; Zhang, Xiaoyoung; Matsumura, Kazuhiko; Sayo, Noboru; Kumobayashi, Hidenori; Ohta, Tetsuo; Nozaki, Kyoko; Takaya, Hidemasa
Journal of Organic Chemistry, 1996 , vol. 61, # 16 p. 5510 - 5516
