(E)-3-(2-甲基苯基)丙-2-烯酸合成路线 (共 16 条)
反应条件
1: 89 percent / SOCl2 / 2 h / Heating 2: 1.) BuLi / 1.) THF, hexane, r.t., 15 min, 2.) 8 h 3: 15 percent / 0 h / 900 °C / 0 - 0.1 Torr View Scheme
参考文献
Aitken, R. Alan; Boeters, Christine; Morrison, John J.
Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 17 p. 2625 - 2631
反应条件
sulfuric acid; mercury(II) diacetate; bromate anion in water; acetic acid Mechanism;
参考文献
Reddy, Ch. Sanjeeva; Sundaram, E. V.
Tetrahedron, 1989 , vol. 45, # 7 p. 2109 - 2126
反应条件
sulfuric acid; mercury(II) diacetate; bromate anion in water; acetic acid effect of solvent polarity, temperature, mercury acetate on oxidation ΔH(excit.), ΔS(excit.), ΔG(excit.); MechanismKineticsThermodynamic data;
参考文献
Reddy, Ch. Sanjeeva; Sundaram, E. V.
Tetrahedron, 1989 , vol. 45, # 7 p. 2109 - 2126
反应条件
thionyl chloride 2 h; Heating;
参考文献
Aitken, R. Alan; Boeters, Christine; Morrison, John J.
Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 17 p. 2625 - 2631
反应条件
carbon dioxide; Taxus chinensis phenylalanine aminomutase; ammonia in water pH=10; Enzymatic reaction; Kinetics; optical yield given as percent eeenantioselective reaction;
参考文献
Szymanski, Wiktor; Wu, Bian; Weiner, Barbara; De Wildeman, Stefaan; Feringa, Ben L.; Janssen, Dick B.
Journal of Organic Chemistry, 2009 , vol. 74, # 23 p. 9152 - 9157
反应条件
1: 89 percent / SOCl2 / 2 h / Heating 2: 1.) BuLi / 1.) THF, hexane, r.t., 15 min, 2.) 8 h 3: 9 percent / 0 h / 900 °C / 0 - 0.1 Torr View Scheme
参考文献
Aitken, R. Alan; Boeters, Christine; Morrison, John J.
Journal of the Chemical Society - Perkin Transactions 1, 1997 , # 17 p. 2625 - 2631
反应条件
oxygen; NADPH in various solvent(s) T=30°C; Enzyme kinetics;
参考文献
Chen, Hao; Jiang, Hanxiao; Morgan, John A.
Phytochemistry, 2007 , vol. 68, # 3 p. 306 - 311
反应条件
nitric acid; nickel(II) nitrate hexahydrate T=20°C; nitro Hunsdiecker reaction; 1.5 h;
参考文献
Ramgopal; Ramesh; Chakradhar; Reddy, N. Maasi; Rajanna
Tetrahedron Letters, 2007 , vol. 48, # 23 p. 4043 - 4045
反应条件
palladium 10 on activated carbon; hydrogen in methanol T=20°C;
参考文献
MERIAL LIMITED; MENG, Charles, Q.
Patent: WO2013/74892 A1, 2013 ;
Location in patent: Page/Page column 39-40 ;
反应条件
1: palladium 10 on activated carbon; hydrogen / methanol / 20 °C 2: trifluorormethanesulfonic acid / 20 °C View Scheme
参考文献
MERIAL LIMITED; MENG, Charles, Q.
Patent: WO2013/74892 A1, 2013 ;