3,4-环氧-1-丁烯合成路线 （共 241 条）
反应条件
1: 1-(trimethylsilyl)-1-propyne With n-butyllithium in tetrahydrofuran; diethyl ether
T=-25 - 0°C; 1.25 h; Inert atmosphere;
2: Butadiene monooxide in tetrahydrofuran; diethyl ether
T=-25 - 20°C; Inert atmosphere;
参考文献
Ramharter, Juergen; Mulzer, Johann
European Journal of Organic Chemistry, 2012 , # 10 p. 2041 - 2053
参考文献
Imahori, Tatsushi; Ojima, Hidetomo; Tateyama, Hiroki; Mihara, Yukiko; Takahata, Hiroki
Tetrahedron Letters, 2008 , vol. 49, # 2 p. 265 - 268
反应条件
1: With triethylamine; bis(η3-allyl-μ-chloropalladium(II)) in dichloromethane
T=35°C; 18 h;
2: With lithium hydroxide in tetrahydrofuran; water
T=20°C; 20 h; Further stages. Title compound not separated from byproducts.;
参考文献
Trost, Barry M.; Fandrick, Daniel R.; Brodmann, Tobias; Stiles, Dylan T.
Angewandte Chemie - International Edition, 2007 , vol. 46, # 32 p. 6123 - 6125
反应条件
1: With triethylamine; bis(η3-allyl-μ-chloropalladium(II)) in dichloromethane
T=35°C; 18 h;
2: With lithium hydroxide in tetrahydrofuran; water
T=20°C; 20 h; Further stages. Title compound not separated from byproducts.;
参考文献
Trost, Barry M.; Fandrick, Daniel R.; Brodmann, Tobias; Stiles, Dylan T.
Angewandte Chemie - International Edition, 2007 , vol. 46, # 32 p. 6123 - 6125
参考文献
Gurevich, P. A.; Musabekova, Z. R.; Zykova, T. V.; Lukonin, D. E.
Russian Journal of General Chemistry, 1994 , vol. 64, # 1.2 p. 149 - 150
Zhurnal Obshchei Khimii, 1994 , vol. 64, # 1 p. 164
反应条件
in diethyl ether
6 h; Ambient temperature; Yield given. Yields of byproduct given;
参考文献
Yamada, Jun-ichi; Yumoto, Masatoshi; Yamamoto, Yoshinori
Tetrahedron Letters, 1989 , vol. 30, # 32 p. 4255 - 4258
反应条件
O,O'-(R)-(1,1'-dinaphthyl-2,2'-diyl)-N,N'-di-(R,R)-1-phenylethylphosphoramidite; copper(II) bis(trifluoromethanesulfonate) in toluene
T=-78 - 0°C; 5 h; Title compound not separated from byproducts;
参考文献
Pineschi, Mauro; Del Moro, Federica; Crotti, Paolo; Di Bussolo, Valeria; Macchia, Franco
Journal of Organic Chemistry, 2004 , vol. 69, # 6 p. 2099 - 2105
反应条件
1,4-dioxane; diethyl ether
参考文献
Freedman; Becker
Journal of Organic Chemistry, 1951 , vol. 16, p. 1701,1708
参考文献
Freedman; Becker
Journal of Organic Chemistry, 1951 , vol. 16, p. 1701,1708
参考文献
Kociolek, Martin G.; Hongfa, Chayanant
Tetrahedron Letters, 2003 , vol. 44, # 9 p. 1811 - 1813
