1-苯基-1,3-丁二酮合成路线 （共 471 条）
反应条件
aluminasuported sodium carbonate; silica gelsuported polyphosphoric acid in toluene
T=80°C; 2 h;
参考文献
Aoyama, Tadashi; Nagaoka, Takashi; Takido, Toshio; Kodomari, Mitsuo
Synthesis, 2011 , # 4 art. no. F18910SS, p. 619 - 625
反应条件
ammonium cerium (IV) nitrate in methanol; water; acetonitrile
T=-20°C; 0.25 h;
参考文献
Song, Jianan; Zhang, Hao; Chen, Xianjun; Li, Xinsheng; Xu, Dongcheng
Synthetic Communications, 2010 , vol. 40, # 12 p. 1847 - 1855
反应条件
perchloric acid in acetonitrile
Ambient temperatureconstant current electrolysis, 30 mA, 1 mA/cm2; Yield given. Title compound not separated from byproducts;
参考文献
Ohmori, Hidenobu; Maeda, Hatsuo; Tamaoka, Mie; Masui, Masaichiro
Chemical and Pharmaceutical Bulletin, 1988 , vol. 36, # 2 p. 613 - 620
参考文献
Sachs
Justus Liebigs Annalen der Chemie, 1909 , vol. 365, p. 162
参考文献
Sachs
Justus Liebigs Annalen der Chemie, 1909 , vol. 365, p. 162
反应条件
potassium carbonate in dimethyl sulfoxide
T=20°C;
参考文献
Rahn, Thomas; Bendrath, Franziska; Hein, Martin; Baumann, Wolfgang; Jiao, Haijun; Boerner, Armin; Villinger, Alexander; Langer, Peter
Organic and Biomolecular Chemistry, 2011 , vol. 9, # 14 p. 5172 - 5184
反应条件
potassium carbonate in N,N-dimethyl-formamide
T=50°C; 3 h;
参考文献
Podder, Ranjan Kumar; Sarkar, Ranjit Kumar; Ray, Suvas C.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1988 , vol. 27, p. 530 - 536
反应条件
in water
4 h; Reflux; regioselective reaction;
参考文献
Aggarwal, Ranjana; Sumran, Garima; Garg, Neelam; Aggarwal, Ashok
European Journal of Medicinal Chemistry, 2011 , vol. 46, # 7 p. 3038 - 3046
反应条件
1: ammonium cerium (IV) nitrate; 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical; oxygen / ethyl acetate / 36 h / 60 °C / 760.05 Torr / |Schlenk technique; |Molecular sieve
2: sodium acetate / acetonitrile / 12 h / 80 °C / 760.05 Torr / |Schlenk technique; |Inert atmosphere
View Scheme
参考文献
Feng, Peng; Sun, Xiang; Su, Yijin; Li, Xinyao; Zhang, Li-He; Shi, Xiaodong; Jiao, Ning
Organic Letters, 2014 , vol. 16, # 12 p. 3388 - 3391
反应条件
1,8-diazabicyclo[5.4.0]undec-7-ene in tert-butyl alcohol
3 h; Heating;
参考文献
Marquet, Jorge; Moreno-Manas, Marcial; Pacheco, Pedro; Prat, Maria; Katritzky, Alan R.; Brycki, Bogumil
Tetrahedron, 1990 , vol. 46, # 15 p. 5333 - 5346
