O,O'-(R)-(1,1'-dinaphthyl-2,2'-diyl)-N,N'-di-(R,R)-1-phenylethylphosphoramidite; copper(II) bis(trifluoromethanesulfonate) in toluene T=-78 - 0°C; 5 h; Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 69, # 6 p. 2099 - 2105
oxygen; rose bengal; triphenylphosphine multistep reaction: 1.) EtOH, 25 deg C, irradiation; other temperature (50 deg C); photosensitised oxidation of olefins, reduction of the hydroperoxides formed; Product distribution;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 11 p. 2715 - 2718
Cl2Ni(1,2-bis(diphenylphosphino)ethane) 5 h; Ambient temperatureregio- and stereoselectivity of Ni-catalyzed alkylation; various Grignard reagents; Product distribution;