2-甲基-1-戊烯-3-炔合成路线 （共 34 条）
反应条件
methylaluminoxane in benzene-d6
T=20°C; Dimerization; P=1E-05 Torr; 48 h;
参考文献
Dash, Aswini K.; Eisen, Moris S.
Organic Letters, 2000 , vol. 2, # 6 p. 737 - 740
反应条件
nonafluoro-n-butanesulfonyl fluoride; phosphazene base P1-t-bu-tris(tetramethylene) in 1-methyl-pyrrolidin-2-one
T=-10 - 20°C;
参考文献
Lyapkalo, Ilya M.; Vogel, Michael A. K.; Boltukhina, Ekaterina V.; Vavrik, Jiri
Synlett, 2009 , # 4 p. 558 - 561
反应条件
diethyl ether
T=0°C;
参考文献
Sacharowa
Zhurnal Obshchei Khimii, 1947 , vol. 17, p. 689
Chem.Abstr., 1948 , p. 1871
Full Text Show Details
Hurd; Cohen
Journal of the American Chemical Society, 1931 , vol. 53, p. 1073
反应条件
bis(η3-allyl)palladium-triisopropylphosphine in toluene
T=110°C; 42 h; Further byproducts given;
参考文献
Deohring, A.; Jolly, P. W.
Tetrahedron Letters, 1980 , vol. 21, p. 3021 - 3024
反应条件
bis(η3-allyl)palladium-bisdicyclohexylphosphino-ethene in toluene
T=90°C; 72 h; Further byproducts given;
参考文献
Deohring, A.; Jolly, P. W.
Tetrahedron Letters, 1980 , vol. 21, p. 3021 - 3024
反应条件
bis(η3-allyl)palladium-bisdicyclohexylphosphino-ethene in toluene
T=90°C; 72 h; other solvents eg. DMF, other catalisators also were used; Further byproducts given;
参考文献
Deohring, A.; Jolly, P. W.
Tetrahedron Letters, 1980 , vol. 21, p. 3021 - 3024
反应条件
N-ethyl-N,N-diisopropylamine; trifluoroacetic anhydride in dichloromethane
1) -78 deg C, 2) -40 deg C, 30 min;
参考文献
Hoffmann, H. M. R.; Matthei, Juergen
Chemische Berichte, 1980 , vol. 113, # 12 p. 3837 - 3847
反应条件
N-ethyl-N,N-diisopropylamine in dichloromethane
1) -78 deg C, 2) -40 deg C, 30 min;
参考文献
Hoffmann, H. M. R.; Matthei, Juergen
Chemische Berichte, 1980 , vol. 113, # 12 p. 3837 - 3847
反应条件
1: (i) NaNH2, liq. NH3, Et2O, (ii) /BRN= 969135/
2: Et3N / CHCl3 / 35 °C
3: aq. HCl / Heating
View Scheme
参考文献
Easton,N.R. et al.
Journal of Organic Chemistry, 1965 , vol. 30, p. 3084 - 3088
反应条件
1: Et3N / CHCl3 / 35 °C
2: aq. HCl / Heating
View Scheme
参考文献
Easton,N.R. et al.
Journal of Organic Chemistry, 1965 , vol. 30, p. 3084 - 3088
