trans-2-甲基戊二烯合成路线 (共 25 条)
反应条件
hydrogen; lt;Co(SCN)(PPh3)3gt; in ethylene glycol dimethyl ether
T=17°C; P=760 Torr; relative rate; rate of H2 uptake;; Product distributionMechanism;
参考文献
Nakayama; Kanai
Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 1 p. 16 - 22
参考文献
Gassman, Paul G.; Singleton, Daniel A.; Wilwerding, James J.; Chavan, Subhash P.
Journal of the American Chemical Society, 1987 , vol. 109, # 7 p. 2182 - 2184
反应条件
1: With iron; zinc(II) iodide; zinc; CoBr2{N-[(pyridin-2-yl)methylene]methanesulfonamide} in dichloromethane
T=20°C; Diels-Alder reaction; 24 h;
2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone in benzene
T=20°C;
参考文献
Hilt, Gerhard; Janikowski, Judith; Hess, Wilfried
Angewandte Chemie - International Edition, 2006 , vol. 45, # 31 p. 5204 - 5206
反应条件
(i) K, Et3N, (ii) /BRN= 969135/; Multistep reaction;
参考文献
Yasuda,H. et al.
Bulletin of the Chemical Society of Japan, 1979 , vol. 52, p. 2036 - 2045
反应条件
Yield given. Multistep reaction;
参考文献
Murphy, Roger; Prager, Rolf H.
Australian Journal of Chemistry, 1981 , vol. 34, # 1 p. 143 - 150