trans-2-甲基戊二烯合成路线 （共 25 条）
反应条件
1: H2O; tetrahydrofuran / 72 h / 0 °C 2: 1.49 g / 1.) H2, 2.) HCl / 1.) Pd(OH)2 / 1.) EtOH, 24 h, 2.) MeOH View Scheme
参考文献
Waldmann, Herbert
Liebigs Annalen der Chemie, 1989 , p. 231 - 238
反应条件
hydrogen; lt;Co(SCN)(PPh3)3gt; in ethylene glycol dimethyl ether T=17°C; P=760 Torr; relative rate; rate of H2 uptake;; Product distributionMechanism;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 58, # 1 p. 16 - 22
反应条件
hydrogen; potassium cyanide; potassium hydroxide; potassium chloride; β-cyclodextrin; cobalt(II) chloride in benzene P=760 Torr; 50 h; Ambient temperature; Yield given. Yields of byproduct given;
参考文献
Lee, Jong-Tae; Alper, Howard
Journal of Organic Chemistry, 1990 , vol. 55, # 6 p. 1854 - 1856
反应条件
hydrogen; lt;Co(SCN)(PPh3)3gt; in ethylene glycol dimethyl ether T=17°C; P=760 Torr; relative rate; rate of H2 uptake;; Product distributionMechanism;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 58, # 1 p. 16 - 22
反应条件
in pentane
T=23°C; Irradiation; Further byproducts given;
参考文献
Fahie, Brian J.; Leigh, William J.
Canadian Journal of Chemistry, 1989 , vol. 67, p. 1859 - 1867
反应条件
triethylamine; triphenylphosphine
1.) toluene, overnight, 2.) THF-d8, 50 deg C, 4 h; Yield given. Multistep reaction;
参考文献
Zhong, Zhandong; Hinkle, Robert J.; Arif, Atta M.; Stang, Peter J.
Journal of the American Chemical Society, 1991 , vol. 113, # 16 p. 6196 - 6202
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=220°C;
参考文献
Diab, J.; Abou-Assali, M.; Gervais, C.; Anker, D.
Tetrahedron Letters, 1985 , vol. 26, # 12 p. 1501 - 1502
反应条件
hydrogen bromide in water
Dehydration;
参考文献
Viktorov; Zubritskii
Russian Journal of Organic Chemistry, 1999 , vol. 35, # 12 p. 1755 - 1765
参考文献
Stakem, Francis, G.; Heck, Richard F.
Journal of Organic Chemistry, 1980 , vol. 45, # 18 p. 3584 - 3593
反应条件
DpSc-H
T=80°C; Product distribution;
参考文献
Bunel, Emilio; Burger, Barbara J.; Bercaw, John E.
Journal of the American Chemical Society, 1988 , vol. 110, # 3 p. 976 - 978
