(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in tetrahydrofuran T=80°C; 12 h; Inert atmosphere;

n-butyllithium; zinc(II) chloride; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 1.) hexane, THF, 0 deg C, 3.5 h; 2.) hexane, THF, a.) 0 deg C, 4.5 h; b.) RT, 15 h; Yield given. Multistep reaction. Yields of byproduct given;

n-butyllithium; bromine 1.) THF, hexane, 0 deg C, 4 h; 2.) THF, hexane, a.) -78 deg C; b.) 0 deg C, 10 min; Yield given. Multistep reaction. Yields of byproduct given;

2 h; Ambient temperature;