3: 85 percent / conc. HCl / aq. ethanol / 8 h / Heating View Scheme

暂无反应条件数据

trifluoroacetic acid T=95°C; 5 h;

1,3,5,7-tetra-azatricyclo[5.1.1.13,5]decane 12 h; Heating;

1: 23 percent / ICl / CH2Cl2 / 1.) RT, 1 h, 2.) reflux, 20 min 2: 1.) n-BuLi / 1.) ether, hexane, 10 min, 2.) ether, hexane, a) RT, 10 min, b) reflux, 10 min View Scheme

1: sodium hydrosulfite / alkaline solution 2: sulfuryl chloride 3: 68 percent / N-bromosuccinimide, dibenzoil peroxide / CCl4 / Heating 4: 63 percent View Scheme

1: sulfuryl chloride 2: 68 percent / N-bromosuccinimide, dibenzoil peroxide / CCl4 / Heating 3: 63 percent View Scheme

1: 68 percent / N-bromosuccinimide, dibenzoil peroxide / CCl4 / Heating 2: 63 percent View Scheme

n-butyllithium 1.) ether, hexane, 10 min, 2.) ether, hexane, a) RT, 10 min, b) reflux, 10 min; Yield given. Multistep reaction. Yields of byproduct given;

1: 65 percent / NaH / EtOH / toluene / 1 h / Ambient temperature 2: 70 percent / NaOAc / 3 h / 140 °C 3: 78 percent / LiAlH4 / tetrahydrofuran / 24 h / Ambient temperature 4: 90 percent / Et3N, DMAP / CH2Cl2 / 5 h / Ambient temperature 5: 90 percent / cerium(IV) ammonium nitrate / acetonitrile; H2O / 3 h / Ambient temperature 6: 84 percent / AlCl3 / CH2Cl2 / 1 h / Ambient temperature 7: 75 percent / 1 h / 100 °C 8: 95 percent / AlCl3 / CH2Cl2 / 24 h / Ambient temperature 9: 98 percent / 10percent aq. NaOH / 24 h / Ambient temperature View Scheme