4,4,5,5,6,6,7,7,8,8,9,9,9-十三氟壬基碘化物合成路线 （共 9 条）
89889-20-34,4,5,5,6,6,7,7,8,8,9,9,9-十三氟壬基碘化物
→
反应条件
sodium hydroxide in ethanol T=30°C; Rate constant;
参考文献
Brace, Neal O.; Marshall, Lawrence W.; Pinson, Carol J.; Wingerden, Gail van
Journal of Organic Chemistry, 1984 , vol. 49, # 13 p. 2361 - 2368
→
89889-20-34,4,5,5,6,6,7,7,8,8,9,9,9-十三氟壬基碘化物
反应条件
1H-imidazole; iodine; triphenylphosphine in dichloromethane
T=0 - 20°C;
参考文献
Kojima, Masaru; Nakamura, Yutaka; Ishikawa, Takuma; Takeuchi, Seiji
Tetrahedron Letters, 2006 , vol. 47, # 35 p. 6309 - 6314
→
89889-20-34,4,5,5,6,6,7,7,8,8,9,9,9-十三氟壬基碘化物
反应条件
1: 92.6 percent / KOH / ethanol; H2O / 3 h / 69 - 70 °C
2: 85percent H3PO4, KI, P2O5 / 6 h / 127 - 135 °C
View Scheme
参考文献
Brace, Neal O.; Marshall, Lawrence W.; Pinson, Carol J.; Wingerden, Gail van
Journal of Organic Chemistry, 1984 , vol. 49, # 13 p. 2361 - 2368
→
89889-20-34,4,5,5,6,6,7,7,8,8,9,9,9-十三氟壬基碘化物
反应条件
phosphoric acid; phosphorus pentoxide; potassium iodide
T=127 - 135°C; 6 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Brace, Neal O.; Marshall, Lawrence W.; Pinson, Carol J.; Wingerden, Gail van
Journal of Organic Chemistry, 1984 , vol. 49, # 13 p. 2361 - 2368
→
89889-20-34,4,5,5,6,6,7,7,8,8,9,9,9-十三氟壬基碘化物
反应条件
1: 89 percent / LiAlH4 / tetrahydrofuran
2: 75 percent / PPh3; I2; imidazole / CH2Cl2 / 0 - 20 °C
View Scheme
参考文献
Kojima, Masaru; Nakamura, Yutaka; Ishikawa, Takuma; Takeuchi, Seiji
Tetrahedron Letters, 2006 , vol. 47, # 35 p. 6309 - 6314
89889-20-34,4,5,5,6,6,7,7,8,8,9,9,9-十三氟壬基碘化物
→
反应条件
sodium hydroxide in ethanol
T=30°C; Rate constant;
参考文献
Brace, Neal O.; Marshall, Lawrence W.; Pinson, Carol J.; Wingerden, Gail van
Journal of Organic Chemistry, 1984 , vol. 49, # 13 p. 2361 - 2368
89889-20-34,4,5,5,6,6,7,7,8,8,9,9,9-十三氟壬基碘化物
→
反应条件
in methanol
T=30°C; variation of condition; Product distribution;
参考文献
Brace, Neal O.; Marshall, Lawrence W.; Pinson, Carol J.; Wingerden, Gail van
Journal of Organic Chemistry, 1984 , vol. 49, # 13 p. 2361 - 2368
89889-20-34,4,5,5,6,6,7,7,8,8,9,9,9-十三氟壬基碘化物
→
反应条件
sodium hydroxide in ethanol
T=30°C; Rate constant;
参考文献
Brace, Neal O.; Marshall, Lawrence W.; Pinson, Carol J.; Wingerden, Gail van
Journal of Organic Chemistry, 1984 , vol. 49, # 13 p. 2361 - 2368
89889-20-34,4,5,5,6,6,7,7,8,8,9,9,9-十三氟壬基碘化物
→
反应条件
in methanol
T=30°C; variation of condition; Product distribution;
参考文献
Brace, Neal O.; Marshall, Lawrence W.; Pinson, Carol J.; Wingerden, Gail van
Journal of Organic Chemistry, 1984 , vol. 49, # 13 p. 2361 - 2368
