1,3-双(二苯基膦甲基)苯合成路线 （共 7 条）
反应条件
1: bis-diphenylphosphine With n-butyllithium in tetrahydrofuran; hexane
T=-40 - 0°C; Metallation;
2: 1,3-bis-(chloromethyl)benzene in tetrahydrofuran; hexane
T=20°C; Condensation; Heating; Further stages.;
参考文献
Cohen, Revital; Van Der Boom, Milko E.; Shimon, Linda J. W.; Rozenberg, Haim; Milstein, David
Journal of the American Chemical Society, 2000 , vol. 122, # 32 p. 7723 - 7734
反应条件
in tetrahydrofuran
T=20°C; 6.16667 h; Inert atmosphere;
参考文献
Arunachalampillai, Athimoolam; Loganathan, Nagarajan; Wendt, Ola F.
Polyhedron, 2012 , vol. 32, # 1 p. 24 - 29
反应条件
1: Li / tetrahydrofuran
2: tetrahydrofuran
View Scheme
参考文献
Ashton, Peter R.; Calcagno, Patrizia; Spencer, Neil; Harris, Kenneth D. M.; Philp, Douglas
Organic Letters, 2000 , vol. 2, # 10 p. 1365 - 1368
反应条件
1: With α,α,α-trifluorotoluene
Reflux;
2: With trichlorosilane
3 h; Reflux;
参考文献
Duncan, Daniel; Hope, Eric G.; Singh, Kuldip; Stuart, Alison M.
Dalton Transactions, 2011 , vol. 40, # 9 p. 1998 - 2005
反应条件
1: in acetone
T=55°C;
2: With sodium acetate in water
Further stages.;
参考文献
Kozhanov, Konstantin A.; Bubnov, Michael P.; Cherkasov, Vladimir K.; Vavilina, Nina N.; Efremova, Larisa Yu.; Artyushin, Oleg. I.; Odinets, Irina L.; Abakumov, Gleb A.
Dalton Transactions, 2008 , # 21 p. 2849 - 2853
反应条件
in tetrahydrofuran
Condensation;
参考文献
Ashton, Peter R.; Calcagno, Patrizia; Spencer, Neil; Harris, Kenneth D. M.; Philp, Douglas
Organic Letters, 2000 , vol. 2, # 10 p. 1365 - 1368
参考文献
Rimml, Heinrich; Venanzi, Luigi M.
Journal of Organometallic Chemistry, 1983 , vol. 259, # 1 p. C6 - C7
