trichlorosilane; dihydrogen hexachloroplatinate Heating;

sodium hydrogencarbonate; tetrakis(triphenylphosphine) palladium(0) in xylene T=130°C; 16 h; Yield given. Yields of byproduct given;

1: 79 percent / pyridine / benzene / 1 h 2: 55 percent / n-Bu3SnH, AIBN / neat (no solvent) / Heating View Scheme

sodium hydrogencarbonate; tetrakis(triphenylphosphine) palladium(0) in xylene T=130°C; 16 h; Yield given. Yields of byproduct given;

Yield given. Multistep reaction;

暂无反应条件数据

triethylamine in dichloromethane T=20°C; 1 h;

1: 93 percent / pyridine / CH2Cl2 / 24 h / -5 - 25 °C 2: 98 percent / Et3N; SOCl2 / CH2Cl2 / 5 h / 0 - 25 °C 3: 32 percent / Cs2CO3 / CH2Cl2 / 72 h / 25 °C 4: 89 percent / LiAlH4 / tetrahydrofuran / 4 h / Heating 5: 68 percent / imidazole; PPh3; I2 / diethyl ether; acetonitrile / 24 h / 25 °C 6: 67 percent / LiCl; CuCl2 / tetrahydrofuran / 24 h / -5 - 20 °C View Scheme