2-(三甲基硅)苯基三氟甲烷磺酸盐合成路线 （共 525 条）
反应条件
cesium fluoride in acetonitrile T=20°C; 5 h;
参考文献
Liu, Zhijian; Larock, Richard C.
Journal of Organic Chemistry, 2006 , vol. 71, # 8 p. 3198 - 3209
反应条件
potassium fluoride; 18-crown-6 ether; water in tetrahydrofuran T=30°C; 16 h; Inert atmosphere;
参考文献
Kaicharla, Trinadh; Thangaraj, Manikandan; Biju, Akkattu T.
Organic Letters, 2014 , vol. 16, # 6 p. 1728 - 1731
反应条件
cesium fluoride in acetonitrile T=80°C; regioselective reaction;
参考文献
Organic Letters, , vol. 15, # 13 p. 3444 - 3447
反应条件
1: morpholine With N-chloro-succinimide in acetonitrile 1 h; 2: o-(trimethylsilyl)phenyl trifluoromethanesulfonate With cesium fluoride T=60°C; regioselective reaction;
参考文献
Organic Letters, , vol. 15, # 13 p. 3444 - 3447
反应条件
1: o-(trimethylsilyl)phenyl trifluoromethanesulfonate With potassium fluoride; 18-crown-6 ether; tri-n-butyl-tin hydride; hydroquinone in tetrahydrofuran T=20°C; 2 h; Inert atmosphere; 2: para-nitro iodo-benzene With copper(l) iodide; bis(η3-allyl-μ-chloropalladium(II)); triphenylphosphine in N,N-dimethyl-formamide T=60°C; Stille coupling; 16 h; Inert atmosphere;
参考文献
Lakshmi, B. Vasantha; Wefelscheid, Ulrike K.; Kazmaier, Uli
Synlett, 2011 , # 3 art. no. G36110ST, p. 345 - 348
反应条件
triphenylphosphine; cesium fluoride in toluene; acetonitrile T=50°C; 5.5 h;
参考文献
Hong, Deng; Chen, Zhengbo; Lin, Xufeng; Wang, Yanguang
Organic Letters, 2010 , vol. 12, # 20 p. 4608 - 4611
反应条件
fluoride in tetrahydrofuran Ambient temperature;
参考文献
Cobas, Agustin; Guitian, Enrique; Castedo
Journal of Organic Chemistry, 1997 , vol. 62, # 15 p. 4896 - 4897
反应条件
1: With cesium fluoride in toluene; acetonitrile T=110°C; 48 h; Inert atmosphereSealed vial; 2: With trifluoroacetic acid T=20°C; 0.333333 h;
参考文献
Pirali, Tracey; Zhang, Fengzhi; Miller, Anna H.; Head, Jenna L.; McAusland, Donald; Greaney, Michael F.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 4 p. 1006 - 1009
反应条件
1: N-tritylaniline With THF-d8 (tetrahydrofuran-d8); water-d2; sodium hydroxide T=20°C; 24 h; 2: o-(trimethylsilyl)phenyl trifluoromethanesulfonate With acetonitrile-D3; cesium fluoride in toluene Inert atmosphereSealed vialReflux; 3: With trifluoroacetic acid T=20°C; 0.333333 h;
参考文献
Angewandte Chemie - International Edition, , vol. 51, # 4 p. 1006 - 1009
反应条件
potassium fluoride; 18-crown-6 ether in tetrahydrofuran T=0°C; 10 h;
参考文献
Yoshida, Hiroto; Mimura, Yasuhiro; Ohshita, Joji; Kunai, Atsutaka
Chemical Communications, 2007 , # 23 p. 2405 - 2407
