4-甲基-3-(4,4,5,5-四甲基-1,3,2-二氧硼烷)-苯甲酸甲酯合成路线 （共 4 条）
反应条件
dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct; potassium acetate in dimethyl sulfoxide T=80°C; Inert atmosphere;
参考文献
3-V BIOSCIENCES, INC.; OSLOB, Johan D.; MCDOWELL, Robert S.; JOHNSON, Russell; YANG, Hanbiao; EVANCHIK, Marc; ZAHARIA, Cristiana A.; CAI, Haiying; HU, Lily W.
Patent: WO2014/8197 A1, 2014 ;
Location in patent: Page/Page column 71; 72 ;
反应条件
1: With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II); potassium acetate in 1,4-dioxane T=100°C; 0.0833333 h; Inert atmosphere; 2: With triethylamine in 1,4-dioxane T=100°C; 12 h; Inert atmosphere;
参考文献
Li, Hengye; Wang, Heye; Liu, Yunchun; Liu, Zhen
Chemical Communications, 2012 , vol. 48, # 34 p. 4115 - 4117
反应条件
Et3N; tetrabutylammonium iodide; 1,1'-bis-(di-tert-butylphosphino)ferrocene; bis(dibenzylideneacetone)-palladium(0) in 1,4-dioxane 100°C, 96 h; GC;
参考文献
Murata, Miki; Oda, Takeshi; Sogabe, Yosuke; Tone, Hirofumi; Namikoshi, Takeshi; Watanabe, Shinji
Chemistry Letters, 2011 , vol. 40, # 9 p. 962 - 963
反应条件
1: sulfuric acid / 0 - 60 °C 2: potassium acetate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct / dimethyl sulfoxide / 80 °C / |Inert atmosphere View Scheme
