dipotassium peroxodisulfate; silver nitrate in water; acetonitrile
T=70°C; 2 h;
参考文献
Giles, Robin G.F.; Green, Ivan R.; Hugo, Victor I.; Mitchell, Peter R.K.; Yorke, Selwyn C.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 10 p. 2309 - 2313
in benzene-d6
dissolved acylquinone and allylstannane stood for 24 h under Ar; further standing for 24 h; column chromy. (silica gel); fractions collected; concetrated; NMR;
参考文献
Maruyama; Matano
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 12 p. 3877 - 3885
in dichloromethane
byproducts: 5-acetyl-2H-benzo{h}chromene-6-ol; dissolved acylquinone and allylstannane stood for 20 h under Ar; concd.; column chromy. (silica gel); eluted (hexane/ether); 5-acetyl-2H-benzo(h)chromene-6-ol was obtained with a yield of 3percent; NMR; IR; mass spectra; elem. anal.;
参考文献
Maruyama; Matano
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 12 p. 3877 - 3885
in benzene
byproducts: 5-acetyl-2H-benzo{h}chromene-6-ol; dissolved acylquinone and allylstannane stood for 20 h under Ar; concd.; column chromy. (silica gel); eluted (hexane/ether); 5-acetyl-2H-benzo(h)chromene-6-ol was obtained with a yield of 2percent; NMR; IR; mass spectra; UV/VIS; elem. anal.;
参考文献
Maruyama; Matano
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 12 p. 3877 - 3885
in acetonitrile
dissolved acylquinone and allylstannane stood for 1 h under Ar; concentrated; column chromy. (silica gel); eluted (hexane/ether); 3a-acetyl-2-trimethylstannyl-2,3,3a,4,9,9a-hexahydro-1H-cyclopenta(b)naphthalene-4,9-dione was not obtained; NMR; IR; mass spectra; elem. anal.;
参考文献
Maruyama; Matano
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 12 p. 3877 - 3885
in benzene
byproducts: 2-allyl-3-hydroxy-1,4-naphthoquinone; dissolved acylquinone and allylstannane stood for 21 h under Ar; concd.; column chromy. (silica gel); eluted (hexane/ether); 2-allyl-3-hydroxy-1,4-naphthoquinone was obtained with a yield of 3percent; NMR; IR; mass spectra; elem. anal.;
参考文献
Maruyama; Matano
Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 12 p. 3877 - 3885
