(±)-反式-1,3-二苯基烯丙基乙酸酯合成路线 （共 31 条）
反应条件
potassium carbonate in water; N,N-dimethyl-formamide T=50°C; 84 h;
参考文献
Chevrin, Carole; Le Bras, Jean; Henin, Francoise; Muzart, Jacques
Tetrahedron Letters, 2003 , vol. 44, # 44 p. 8099 - 8102
反应条件
in water; N,N-dimethyl-formamide T=50°C; 24 h;
参考文献
Chevrin, Carole; Le Bras, Jean; Henin, Francoise; Muzart, Jacques
Tetrahedron Letters, 2003 , vol. 44, # 44 p. 8099 - 8102
反应条件
bis(η3-allyl-μ-chloropalladium(II)); (5S,2'R)-4,5-dihydro-2-(2'-diphenylphosphino-2'-phenylethyl)-5-tert-butyl-1,3-oxazole; tetrahexylammonium fluoride in acetonitrile Ambient temperatureother reactant: 2-cyclopentenyl acetate, other reagents: other chiral phosphine-oxazoline ligands/<Pd(η3-C3H5)Cl>2/nBu4NF or nHex4NF or nHex4NBr or TBAOAc or KOAc, NaH presence, other solvents: CH2Cl2, C6H6, THF, other temperature; MechanismProduct distribution;
参考文献
Gilbertson, Scott R.; Chang, Cheng-Wei T.
Journal of Organic Chemistry, 1998 , vol. 63, # 23 p. 8424 - 8431
反应条件
hexadecyltrimethylammonium hydroxide; malonic acid dimethyl ester; (rac)-BINAP; bis(η3-allyl-μ-chloropalladium(II)) in water T=25°C; 1 h;
参考文献
Sinou, Denis; Rabeyrin, Cedric; Nguefack, Christelle
Advanced Synthesis and Catalysis, 2003 , vol. 345, # 3 p. 357 - 363
反应条件
Pd(1,3-dimesityl-imidazole) carbene in tetrahydrofuran T=50°C; Tsuji-Trost reaction; 18 h;
参考文献
Journal of Organometallic Chemistry, , vol. 690, # 24-25 p. 5753 - 5758
反应条件
sodium hydride; (R)-1,1'-bis(diphenylphosphino)-2,2'-binapthyl; palladium/alumina in tetrahydrofuran T=120°C; 3 h; Title compound not separated from byproducts.;
参考文献
Reimann, Sven; Mallat, Tamas; Baiker, Alfons
Journal of Catalysis, 2007 , vol. 252, # 1 p. 30 - 38
反应条件
bis(η3-allyl-μ-chloropalladium(II)); 1-mesityl-3-methyl-imidazol-2-ylidene silver iodide; water; triphenylphosphine; potassium hydroxide in dichloromethane T=20°C; 16 h; Inert atmosphere;
参考文献
European Journal of Inorganic Chemistry, , # 13 SPEC. ISS. p. 1796 - 1805
反应条件
potassium carbonate; acetylacetone; PdCl2(MeCN)2-[(HOCH2CH2HNCOCH2)2NCH2]2 T=50°C; 24 h; Product distribution; Further Variations:SolventsReaction partners;
参考文献
Chevrin, Carole; Le Bras, Jean; Henin, Francoise; Muzart, Jacques
Tetrahedron Letters, 2003 , vol. 44, # 44 p. 8099 - 8102
反应条件
(R,Sp)-josiphos; palladium/alumina T=120°C; 6 h; Quantum yield; Further Variations:CatalystsTemperatures;
参考文献
Reimann, Sven; Mallat, Tamas; Baiker, Alfons
Journal of Catalysis, 2008 , vol. 254, # 1 p. 79 - 83
反应条件
bis(η3-allyl-μ-chloropalladium(II)); (5S,2'R)-4,5-dihydro-2-(2'-diphenylphosphino-2'-phenylethyl)-5-tert-butyl-1,3-oxazole; tetrahexylammonium fluoride in acetonitrile Ambient temperatureother reactant: 2-cyclopentenyl acetate, other reagents: other chiral phosphine-oxazoline ligands/<Pd(η3-C3H5)Cl>2/nBu4NF or nHex4NF or nHex4NBr or TBAOAc or KOAc, NaH presence, other solvents: CH2Cl2, C6H6, THF, other temperature; MechanismProduct distribution;
参考文献
Gilbertson, Scott R.; Chang, Cheng-Wei T.
Journal of Organic Chemistry, 1998 , vol. 63, # 23 p. 8424 - 8431
