1: anhydrous 1-octyne With (.eta.2-1-butene)(trimethylphosphane)zirconocene in tetrahydrofuran
T=20°C;
2: diethyl chlorophosphate in tetrahydrofuran
T=50°C; 6 h; Further stages.;
参考文献
Lai, Chunbo; Xi, Chanjuan; Chen, Chao; Ma, Mingming; Hong, Xiaoyin
Chemical Communications, 2003 , # 21 p. 2736 - 2737
cis-{PdMe2(PMePh2)2} in tetrahydrofuran
T=67°C; 5 h; var. reaction time, var. Pd or Pt compounds as catalysts; other acetylenes, var. solvents, var. temps.; Product distributionMechanism;
参考文献
Han, Li-Biao; Tanaka, Masato
Journal of the American Chemical Society, 1996 , vol. 118, # 6 p. 1571 - 1572
