9,9-二甲基-2,7-芴二硼酸合成路线 (共 5 条)
反应条件
1: With n-butyllithium in tetrahydrofuran; hexane T=-70 - -65°C; 6 h; 2: With tri-isopropoxy-borane in tetrahydrofuran; hexane T=-70 - 20°C; 1 h; 3: With hydrogenchloride in tetrahydrofuran; hexane; water pH=3;
参考文献
IDEMITSU KOSAN CO., LTD.
Patent: EP1860097 A1, 2007 ;
Location in patent: Page/Page column 21; 22 ;
反应条件
1: 2,2’-dibromo-9,9’-dimethyl-fluorene With n-butyllithium in tetrahydrofuran; hexane T=-70 - -65°C; 6 h; Inert atmosphere; 2: tri-isopropoxy-borane in tetrahydrofuran; hexane T=-70 - 20°C; 3: With hydrogenchloride in tetrahydrofuran; hexane; water pH=3;
参考文献
Idemitsu Kosan Co., Ltd.
Patent: US8058450 B2, 2011 ;
Location in patent: Page/Page column 43-44 ;
反应条件
1: With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) in water; toluene
2: in water; toluene
8 h; Heating / reflux;
参考文献
Idemitsu Kosan Co., Ltd.
Patent: US8058450 B2, 2011 ;
Location in patent: Page/Page column 44 ;
反应条件
1: With n-butyllithium in tetrahydrofuran; hexane
T=-70 - -65°C; 6 h;
2: With tri-isopropoxy-borane in tetrahydrofuran; hexane
T=-70 - 20°C; 1 h;
3: With hydrogenchloride in tetrahydrofuran; hexane; water
pH=3;
参考文献
IDEMITSU KOSAN CO., LTD.
Patent: WO2006/100896 A1, 2006 ;
Location in patent: Page/Page column 32; 33 ;
反应条件
1: 2,2’-dibromo-9,9’-dimethyl-fluorene With n-butyllithium in tetrahydrofuran; hexane
T=-70 - -65°C; 6 h; Inert atmosphere;
2: tri-isopropoxy-borane in tetrahydrofuran; hexane
T=-70 - 20°C;
3: With hydrogenchloride in tetrahydrofuran; hexane; water
pH=3;
参考文献
Idemitsu Kosan Co., Ltd.
Patent: US8058450 B2, 2011 ;
Location in patent: Page/Page column 43-44 ;