3,3-二甲基-2,5-己烷二酮合成路线 （共 14 条）
反应条件
sodium hydroxide in water 0.5 h; Heating;
参考文献
Cadman, Michael L. F.; Crombie, Leslie; Freeman, Stephen; Mistry, Jayshree
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1995 , # 11 p. 1397 - 1408
参考文献
Crombie; Mackenzie
Journal of the Chemical Society, 1958 , p. 4417,4426
反应条件
oxygen
T=25°C; 8 h; Irradiation;
参考文献
Macias; Molinillo; Massanet; Rodriguez-Luis
Tetrahedron, 1992 , vol. 48, # 16 p. 3345 - 3352
反应条件
sulfuric acid
T=90°C; 0.416667 h;
参考文献
Cadman, Michael L. F.; Crombie, Leslie; Freeman, Stephen; Mistry, Jayshree
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1995 , # 11 p. 1397 - 1408
反应条件
ozone in chloroform
T=-30°C;
参考文献
Thoai,N.
Bulletin de la Societe Chimique de France, 1964 , p. 225 - 233
参考文献
Corey,E.J.; Hegedus,L.S.
Journal of the American Chemical Society, 1969 , vol. 91, p. 4926 - 4928
反应条件
1: 75 percent / Na / methanol / 24 h / Heating
2: 54 percent / 10percent KOH / methanol / 7 h / Heating
3: 77 percent / H2SO4 / 0.42 h / 90 °C
View Scheme
参考文献
Cadman, Michael L. F.; Crombie, Leslie; Freeman, Stephen; Mistry, Jayshree
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1995 , # 11 p. 1397 - 1408
反应条件
1: 54 percent / 10percent KOH / methanol / 7 h / Heating
2: 77 percent / H2SO4 / 0.42 h / 90 °C
View Scheme
参考文献
Cadman, Michael L. F.; Crombie, Leslie; Freeman, Stephen; Mistry, Jayshree
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1995 , # 11 p. 1397 - 1408
反应条件
hydrogen cation; palladium
Yield given. Multistep reaction;
参考文献
Kosugi, Masanori; Ohashi, Kenji; Akuzawa, Kazuko; Kawazoe, Takashi; Sano, Hiroshi; Migita, Toshihoko
Chemistry Letters, 1987 , p. 1237 - 1238
反应条件
1: 62 percent / Triton B / dioxane; methanol / 12 h / 40 °C
2: 1) 30percent hydrogen peroxide, 2) aq. potassium carbonate / 1) methanol, 0 deg C, 2) 25 deg C, 16h
View Scheme
参考文献
Lui, Kon-Hung; Sammes, Michael P.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , p. 457 - 468
