1H,1H,2H,2H-全氟-1-十二醇合成路线 （共 15 条）
→
17741-60-53,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-二十一氟十二烷醇丙烯酸酯
反应条件
1: 1,1,2,2-tetrafluoroethylene; 1-iodo-pentafluoro-ethane With copper catalyst T=80°C; P=6000.6 Torr; 2: ethene With copper catalyst T=100°C; P=2250.23 Torr; 3 h; 3: acrylic acid potassium salt With 4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
EP1757574 A1, ;
Page/Page column 9 ;
反应条件
hydrogenchloride; water T=70°C; pH=0 - 1; 25 h;
参考文献
Paterova, Jana; Skalicky, Martin; Rybackova, Marketa; Kvicalova, Magdalena; Cvacka, Josef; Kvicala, Jaroslav
Journal of Fluorine Chemistry, 2010 , vol. 131, # 12 p. 1338 - 1343
反应条件
1: 1,1,2,2-tetrafluoroethylene; 1-iodo-pentafluoro-ethane With copper catalyst T=80°C; P=6000.6 Torr; 2: ethene With copper catalyst T=100°C; P=2250.23 Torr; 3 h; 3: acrylic acid potassium salt With 4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
EP1757574 A1, ;
Page/Page column 8-9 ;
反应条件
1: 1,1,2,2-tetrafluoroethylene; 1-iodo-pentafluoro-ethane With copper catalyst T=80°C; P=6000.6 Torr; 2: ethene With copper catalyst T=100°C; P=2250.23 Torr; 3 h; 3: acrylic acid potassium salt With 4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
EP1757574 A1, ;
Page/Page column 9-10 ;
参考文献
EP1757577 A1, ;
Page/Page column 7 ;
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
17741-60-53,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-二十一氟十二烷醇丙烯酸酯
反应条件
4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
EP1757578 A1, ;
Page/Page column 7-8 ;
→
647-42-73,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇+
反应条件
water; silver nitrate; copper(II) sulfate T=180°C; Gas phase; Conversion of starting material;
参考文献
US6664430 B1, ;
Page column 8-9 ;
2043-53-01,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷+
→
反应条件
4-methoxy-phenol; hydroquinone in tert-butyl alcohol T=180 - 190°C; 6 h; Product distribution / selectivity;
参考文献
EP1757578 A1, ;
Page/Page column 6-7; 8-9 ;
反应条件
hydroquinone; toluene-4-sulfonic acid in toluene 4 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757577 A1, 2007 ;
Location in patent: Page/Page column 8-9 ;
反应条件
hydroquinone; toluene-4-sulfonic acid in toluene 4 h; Product distribution / selectivity;
参考文献
DAIKIN INDUSTRIES, LTD.
Patent: EP1757577 A1, 2007 ;
Location in patent: Page/Page column 8-9 ;
