7-脱氮-2'-脱氧鸟苷合成路线 （共 16 条）
反应条件
1: 1) sodium hydride (60percent in oil) / 1) acetonitrile, RT, 0.5 h; 2) acetonitrile, RT, 2 h 2: 86 percent / methanol / 1 h / Heating 3: 92 percent / sodium iodide, chlorotrimethylsilane / acetonitrile View Scheme
参考文献
Journal of Heterocyclic Chemistry, , vol. 25, # 6 p. 1893 - 1898
反应条件
trimethylsilyl iodide
参考文献
Ramasamy; Imamura; Robins; Revankar
Journal of Heterocyclic Chemistry, 1988 , vol. 25, # 6 p. 1893 - 1898
反应条件
1: 1) sodium hydride (60percent in oil) / 1) acetonitrile, RT, 0.5 h; 2) acetonitrile, RT, 2 h 2: 86 percent / methanol / 1 h / Heating 3: 92 percent / sodium iodide, chlorotrimethylsilane / acetonitrile View Scheme
参考文献
Journal of Heterocyclic Chemistry, , vol. 25, # 6 p. 1893 - 1898
反应条件
1: 50percent aq. NaOH / Bu4NHSO4 / CH2Cl2 / Ambient temperature; liquid-liquid phase-transfer glycosylation 2: 2M KOH / 80 °C View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 697 - 702
反应条件
sodium hydroxide 3 h; Heating;
参考文献
Seela, Frank; Westermann, Bernhard; Bindig, Uwe
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1988 , p. 697 - 702
反应条件
sodium hydroxide 4 h; Heating;
参考文献
Seela, Frank; Westermann, Bernhard; Bindig, Uwe
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1988 , p. 697 - 702
反应条件
1: 86 percent / methanol / 1 h / Heating 2: 92 percent / sodium iodide, chlorotrimethylsilane / acetonitrile View Scheme
参考文献
Journal of Heterocyclic Chemistry, , vol. 25, # 6 p. 1893 - 1898
反应条件
1: 54 percent / 50percent aq. NaOH / Bu4NHSO4 / CH2Cl2 / Ambient temperature; liquid-liquid phase-transfer glycosylation 2: 86 percent / 1.0M sodium methoxide / methanol / 12 h / Ambient temperature 3: 86 percent / 2M aq. NaOH / 4 h / Heating View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 697 - 702
反应条件
ammonium hydroxide; dihydrogen peroxide
参考文献
Ramasamy; Imamura; Robins; Revankar
Tetrahedron Letters, 1987 , vol. 28, # 43 p. 5107 - 5110
反应条件
1: 86 percent / 1.0M sodium methoxide / methanol / 12 h / Ambient temperature 2: 86 percent / 2M aq. NaOH / 4 h / Heating View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 697 - 702
