反应条件
1: 78 percent / ceric ammonium nitrate / H2O; acetonitrile / 3-4 h
2: 1.) 6N HCl, sodium nitrite / 1.) -10 deg C; 2.) dioxane, water, 80 deg C, 10 min
3: 85 percent / MnO2 / CH2Cl2 / Ambient temperature; 2-3 h
4: 1.) NaBH4; 2.) MnO2 / 1.) PdCl2(PPh)2 / 1.) methanol, 15 min; 2.) DCM, 30 min
View Scheme
参考文献
Rama Devi; Iyengar; Pardhasaradhi
Tetrahedron, 1994 , vol. 50, # 8 p. 2543 - 2550
