tris-(dibenzylideneacetone)dipalladium(0); N,O-bis-(trimethylsilyl)-acetamide; (S)-1-[4,5-dihydro-4-tert-butyloxazol-2-yl]-1’-[bis(trifluoromethyl)phosphino]ferrocene; sodium acetate in 1,2-dichloro-ethane T=0°C; 12 h; Inert atmosphereSchlenk technique; Catalytic behavior; Reagent/catalystTemperature; Overall yield = 91 percent; enantioselective reaction;

N,O-bis-(trimethylsilyl)-acetamide; C32H30N4O6; sodium hydride; molybdenum hexacarbonate in tetrahydrofuran; mineral oil T=160°C; 0.1 h; Microwave irradiation; optical yield given as percent eeenantioselective reaction;

propylamine; di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium; C29H22NO2P in tetrahydrofuran T=20°C; 12 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;

CF3O3S(1-)*C47H43IrNO2P(1+) in tetrahydrofuran T=20°C; 1 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;

propylamine; di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium; C29H28NO2P in tetrahydrofuran T=20°C; 48 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;

With  di-μ-chloro-bis(η4-1,5-cyclooctadiene)diiridium; samarium diiodide in  tetrahydrofuran T=25°C; 6 h;  Inert atmosphere;  SolventReagent/catalyst;  regioselective reaction;