(4-氰基苯基)三氟硼酸钾合成路线 （共 10 条）
反应条件
1: With potassium fluoride in water; acetonitrile T=21°C; 2: With L-(+)-tartaric acid in tetrahydrofuran; water; acetonitrile
参考文献
Lennox, Alastair J. J.; Lloyd-Jones, Guy C.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 37 p. 9385 - 9388
反应条件
1: With tetrahydroxydiboron; [1,3-bis(diphenylphosphino) propane] dichloronickel(II); N-ethyl-N,N-diisopropylamine; triphenylphosphine in ethanol T=20°C; Miyaura Borylation Reaction; 4 h; Inert atmosphereSealed tube; 2: With potassium hydrogen difluoride in methanol; ethanol; water T=0 - 20°C; 0.5 h;
参考文献
Molander, Gary A.; Cavalcanti, Livia N.; Garcia-Garcia, Carolina
Journal of Organic Chemistry, 2013 , vol. 78, # 13 p. 6427 - 6439
反应条件
1: With tetrahydroxydiboron; [1,3-bis(diphenylphosphino) propane] dichloronickel(II); N-ethyl-N,N-diisopropylamine; triphenylphosphine in ethanol T=50°C; Miyaura Borylation Reaction; 4 h; Inert atmosphereSealed tube; 2: With potassium hydrogen difluoride in methanol; ethanol; water T=0 - 20°C; 0.5 h;
参考文献
Molander, Gary A.; Cavalcanti, Livia N.; Garcia-Garcia, Carolina
Journal of Organic Chemistry, 2013 , vol. 78, # 13 p. 6427 - 6439
反应条件
PdCl(C6H4C6H4NH2)(Cy2PC6H4-2-C6H2-2',4',6'-i-Pr3); Cy2PC6H4-2-C6H2-2',4',6'-i-Pr3; K acetate in ethanol aryl chloride reacted with B2(OH)4 in EtOH in presence of catalyst (Pt-complex - ligand) and K acetate at 80°C for 1 h; subjected to aq. workup; treated with KHF2; purified by Soxlet extn.;
参考文献
Molander, Gary A.; Trice, Sarah L. J.; Kennedy, Steven M.; Dreher, Spencer D.; Tudge, Matthew T.
Journal of the American Chemical Society, 2012 , vol. 134, # 28 p. 11667 - 11673
反应条件
KHF2 in water T=-10 - 20°C; 2 h; Inert atmosphere;
参考文献
European Journal of Organic Chemistry, , # 33 p. 6393 - 6403
反应条件
tert.-butylhydroperoxide; copper(l) chloride in methanol; dichloromethane; water T=0 - 23°C;
参考文献
Dubbaka, Srinivas Reddy; Salla, Manohar; Bolisetti, Raghu; Nizalapur, Shashidhar
RSC Advances, 2014 , vol. 4, # 13 p. 6496 - 6499
反应条件
Oxonereg;; water in acetone T=20°C; 0.0333333 h;
参考文献
Journal of Organic Chemistry, , vol. 76, # 2 p. 623 - 630
反应条件
potassium fluoride; copper(II) bis(trifluoromethanesulfonate) in acetonitrile T=60°C; 20 h; Sealed tube;
参考文献
Ye, Yingda; Schimler, Sydonie D.; Hanley, Patrick S.; Sanford, Melanie S.
Journal of the American Chemical Society, 2013 , vol. 135, # 44 p. 16292 - 16295
反应条件
water; silica gel T=20°C; 24 h; Inert atmosphere;
参考文献
Journal of Organic Chemistry, , vol. 74, # 19 p. 7364 - 7369
反应条件
bis-triphenylphosphine-palladium(II) chloride; potassium carbonate in water; acetonitrile
T=150°C; Suzuki coupling; 0.5 h; Microwave irradiation;
参考文献
Savall, Brad M.; Fontimayor, Jill R.
Tetrahedron Letters, 2008 , vol. 49, # 47 p. 6667 - 6669
