2-[2-(3,4-二氢-6-甲氧基-1(2H)-萘亚基)乙基]-2-乙基环戊烷-1,3-二酮合成路线 （共 4 条）
反应条件
1: aq. HCl / methanol 2: NaBH4 / methanol 3: H2 / Raney-Ni / dioxane 4: Py 5: KOH / methanol 6: Li, liq. NH3 / diethyl ether; dioxane 7: CrO3, aq. H2SO4 / acetone View Scheme
参考文献
Hiraga
Chemical and pharmaceutical bulletin, 1965 , vol. 13, # 11 p. 1289 - 1294
反应条件
1: aq. HCl / methanol 2: NaBH4 / methanol 3: H2 / Raney-Ni / dioxane 4: Li, liq. NH3 / diethyl ether; dioxane View Scheme
参考文献
Hiraga
Chemical and pharmaceutical bulletin, 1965 , vol. 13, # 11 p. 1289 - 1294
反应条件
1: aq. HCl / methanol 2: NaBH4 / methanol 3: H2 / Raney-Ni / dioxane 4: Py 5: KOH / methanol View Scheme
参考文献
Hiraga
Chemical and pharmaceutical bulletin, 1965 , vol. 13, # 11 p. 1289 - 1294
→
3625-82-9(8R,9S,13S,14S,17S)-13-乙基-3-甲氧基-6,7,8,9,11,12,14,15,16,17-十氢环戊烯并[a]菲-17-醇
反应条件
1: aq. HCl / methanol 2: NaBH4 / methanol 3: H2 / Raney-Ni / dioxane 4: Py 5: KOH / methanol 6: Li, liq. NH3 / diethyl ether; dioxane View Scheme
参考文献
Hiraga
Chemical and pharmaceutical bulletin, 1965 , vol. 13, # 11 p. 1289 - 1294
