2,2'-双(二苯基磷)联苯合成路线 （共 10 条）
反应条件
1: With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; Inert atmosphere; 2: With iron (III) acetylacetonate in tetrahydrofuran; hexane T=-78°C; 1 h; Reagent/catalyst;
参考文献
WO2013/7724 A1, ;
Page/Page column 80 ;
反应条件
trichlorosilane; N,N-dimethyl-aniline in toluene Heating;
参考文献
Organic Letters, , vol. 3, # 2 p. 243 - 245
反应条件
1: pyridine 2: 52 percent / DPPB / Pd(OAc)2 / dimethylsulfoxide / 100 °C 3: 91 percent / HSiCl3; PhNMe2 / toluene / Heating View Scheme
参考文献
Organic Letters, , vol. 3, # 2 p. 243 - 245
反应条件
1: 52 percent / DPPB / Pd(OAc)2 / dimethylsulfoxide / 100 °C 2: 91 percent / HSiCl3; PhNMe2 / toluene / Heating View Scheme
参考文献
Organic Letters, , vol. 3, # 2 p. 243 - 245
反应条件
potassium acetate; palladium diacetate in N,N-dimethyl acetamide T=130°C; 3 h; Inert atmosphere;
参考文献
Chemistry - A European Journal, , vol. 17, # 39 p. 11008 - 11016
反应条件
in diethyl ether 1 h; Heating;
参考文献
Journal of Organometallic Chemistry, , vol. 239, # 1 p. 1 - 10
反应条件
1: 78 percent / activated copper / dimethylformamide / 48 h / Heating 2: 71 percent / trichlorosilane, triethylamine / xylene / 1.) 100 deg C, 1 h; 2.) 125 deg C, 1 h; 3.) reflux, 1 h View Scheme
参考文献
Journal of Organometallic Chemistry, , vol. 507, # 1-2 p. 257 - 261
反应条件
1: 1.) phenyllithium, lithium bromide, 2.) iodine / 1.) diethyl ether, -25 deg C, 72 h; 2.) diethyl ether 2: 78 percent / activated copper / dimethylformamide / 48 h / Heating 3: 71 percent / trichlorosilane, triethylamine / xylene / 1.) 100 deg C, 1 h; 2.) 125 deg C, 1 h; 3.) reflux, 1 h View Scheme
参考文献
Journal of Organometallic Chemistry, , vol. 507, # 1-2 p. 257 - 261
反应条件
sodium cyanide in ethanol; water Yield given;
参考文献
Angewandte Chemie, , vol. 99, # 3 p. 262 - 264
反应条件
1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C 1.2: -78 - 20 °C 2.1: potassium acetate; palladium diacetate / N,N-dimethyl acetamide / 3 h / 130 °C / Inert atmosphere View Scheme
参考文献
Chemistry - A European Journal, , vol. 17, # 39 p. 11008 - 11016
