7-(叔-丁基)-1-甲基萘合成路线 （共 12 条）
反应条件
palladium on activated charcoal
T=260 - 290°C; 0.75 h;
参考文献
Jackson, Richard A.; Rhodes, Christopher J.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1993 , # 1 p. 53 - 57
反应条件
selenium
T=360°C; 6 h; sealed tube;
参考文献
Shitole, H. R.; Nayak, U. R.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1983 , vol. 22, # 3 p. 215 - 219
反应条件
1: 57 percent / AlCl3 / various solvent(s)
2: NH2NH2*H2O, KOH / ethane-1,2-diol / 3 h / Heating
3: KOH / ethane-1,2-diol / 12 h / Heating
4: PCl5 / benzene / 0.08 h / Heating
5: SnCl4 / benzene / 6 h / 0 °C
6: 31 percent / diethyl ether / 0.5 h / Heating
7: 80 percent / HCO2H
8: 61 percent / 10percent Pd/C / 0.75 h / 260 - 290 °C
View Scheme
参考文献
Jackson, Richard A.; Rhodes, Christopher J.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1993 , # 1 p. 53 - 57
反应条件
1: 31 percent / diethyl ether / 0.5 h / Heating
2: 80 percent / HCO2H
3: 61 percent / 10percent Pd/C / 0.75 h / 260 - 290 °C
View Scheme
参考文献
Jackson, Richard A.; Rhodes, Christopher J.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1993 , # 1 p. 53 - 57
反应条件
1: PCl5 / benzene / 0.08 h / Heating
2: SnCl4 / benzene / 6 h / 0 °C
3: 31 percent / diethyl ether / 0.5 h / Heating
4: 80 percent / HCO2H
5: 61 percent / 10percent Pd/C / 0.75 h / 260 - 290 °C
View Scheme
参考文献
Jackson, Richard A.; Rhodes, Christopher J.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1993 , # 1 p. 53 - 57
反应条件
1: NH2NH2*H2O, KOH / ethane-1,2-diol / 3 h / Heating
2: KOH / ethane-1,2-diol / 12 h / Heating
3: PCl5 / benzene / 0.08 h / Heating
4: SnCl4 / benzene / 6 h / 0 °C
5: 31 percent / diethyl ether / 0.5 h / Heating
6: 80 percent / HCO2H
7: 61 percent / 10percent Pd/C / 0.75 h / 260 - 290 °C
View Scheme
参考文献
Jackson, Richard A.; Rhodes, Christopher J.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1993 , # 1 p. 53 - 57
反应条件
1: SnCl4 / benzene / 6 h / 0 °C
2: 31 percent / diethyl ether / 0.5 h / Heating
3: 80 percent / HCO2H
4: 61 percent / 10percent Pd/C / 0.75 h / 260 - 290 °C
View Scheme
参考文献
Jackson, Richard A.; Rhodes, Christopher J.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1993 , # 1 p. 53 - 57
反应条件
1: 46 percent / lead tetraacetate / acetic acid / 6 h / 80 °C
2: 1. t-KOBu / 1. ether, 10min; 2. 16h
3: 1. BF3*OEt2; 2. perbenzoic acid / 1. benzene, 16h, reflux; 2. CHCl3, RT
4: 28 percent / Se / 6 h / 360 °C / sealed tube
View Scheme
参考文献
Shitole, H. R.; Nayak, U. R.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1983 , vol. 22, # 3 p. 215 - 219
反应条件
1: 80 percent / HCO2H
2: 61 percent / 10percent Pd/C / 0.75 h / 260 - 290 °C
View Scheme
参考文献
Jackson, Richard A.; Rhodes, Christopher J.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1993 , # 1 p. 53 - 57
反应条件
1: 1. BF3*OEt2; 2. perbenzoic acid / 1. benzene, 16h, reflux; 2. CHCl3, RT
2: 28 percent / Se / 6 h / 360 °C / sealed tube
View Scheme
参考文献
Shitole, H. R.; Nayak, U. R.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1983 , vol. 22, # 3 p. 215 - 219
