1: acetophenone With trimethylsilyl trifluoromethanesulfonate; N-ethyl-N,N-diisopropylamine in dichloromethane
0.25 h; cooling;
2: 1,1-dimethoxyethane in dichloromethane
T=20°C; 2 h; Further stages.;
参考文献
Downey, C. Wade; Johnson, Miles W.; Tracy, Kathryn J.
Journal of Organic Chemistry, 2008 , vol. 73, # 8 p. 3299 - 3302
Alcaide, Benito; Almendros, Pedro; Quiros, M. Teresa; Lopez, Ramon; Menendez, Maria I.; Sochacka-Cwikla, Aleksandra
Journal of the American Chemical Society, 2013 , vol. 135, # 2 p. 898 - 905
1: dihydrogen peroxide; silver nitrate / diethyl ether / 23 h / 0 - 20 °C
2: PPh3 gold(I) chloro complex; silver trifluoromethanesulfonate; toluene-4-sulfonic acid; water / dichloromethane / 20 h / 20 °C
View Scheme
参考文献
Alcaide, Benito; Almendros, Pedro; Quiros, M. Teresa; Lopez, Ramon; Menendez, Maria I.; Sochacka-Cwikla, Aleksandra
Journal of the American Chemical Society, 2013 , vol. 135, # 2 p. 898 - 905