(E)-1-甲基-1,2二苯基乙烯合成路线 （共 175 条）
反应条件
toluene-4-sulfonic acid 1.) THF, room temperature; Multistep reaction. Title compound not separated from byproducts;
参考文献
Journal of the American Chemical Society, , vol. 103, # 11 p. 3002 - 3011
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium hydroxide in tetrahydrofuran; water T=70°C; Suzuki Coupling; 16 h; Inert atmosphere;
参考文献
Journal of the American Chemical Society, , vol. 134, # 37 p. 15165 - 15168
反应条件
1: tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran; 1-methyl-pyrrolidin-2-one / 3 h / 50 °C 2: NiCl2(PPh3)2 / tetrahydrofuran / 12 h / 20 °C / |Inert atmosphere View Scheme
参考文献
Organic and Biomolecular Chemistry, , vol. 11, # 13 p. 2175 - 2185
反应条件
hydrogenchloride in ethanol 1 h; Heating;
参考文献
Petrova, Jordanka; Vassilev, Nikolai G.; Kirilov, Marko
Phosphorus, Sulfur and Silicon and the Related Elements, 1990 , vol. 47, p. 457 - 463
反应条件
n-butyllithium Title compound not separated from byproducts;
参考文献
Journal of the American Chemical Society, , vol. 103, # 11 p. 3002 - 3011
反应条件
palladium diacetate; sodium acetate in acetic acid T=25°C; 24 h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of Organometallic Chemistry, , vol. 465, # 1-2 p. 85 - 92
反应条件
palladium diacetate; sodium acetate in acetic acid T=25°C; 24 h; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of Organometallic Chemistry, , vol. 465, # 1-2 p. 85 - 92
反应条件
1: iodobenzene With lithium chloride; zinc Inert atmosphere; 2: 1,2-propadienylbenzene With [RhCl(η2:η2-cycloocta-1,5-diene)]2; tri-tert-butyl phosphine in tetrahydrofuran; hexane T=66°C; 1.66667 h; Inert atmosphere; 3: With hydrogenchloride; water in tetrahydrofuran; hexane T=25°C;
参考文献
Journal of the American Chemical Society, , vol. 132, # 26 p. 8878 - 8879
反应条件
palladium diacetate; potassium carbonate in PEG-400 T=40°C; Heck type coupling reaction; 18 h; under air;
参考文献
Advanced Synthesis and Catalysis, , vol. 353, # 7 p. 1061 - 1066
反应条件
AlCl3, aluminium chloride T=20°C; Friedel Crafts acylation; 3 h;
参考文献
Journal of the Indian Chemical Society, , vol. 87, # 5 p. 595 - 600
