1,2,3,4,6-alpha-D-葡萄糖五乙酸酯合成路线 （共 153 条）
反应条件
1: HBr; AcOH / 1.5 h / 25 °C 2: 88 percent / Hg(CN)2; derierite / toluene; acetonitrile / 20 °C View Scheme
参考文献
Lin, Chun-Cheng; Yeh, Yi-Chun; Yang, Chan-Yi; Chen, Chan-Long; Chen, Gee-Fong; Chen, Chia-Chun; Wu, Yi-Chun
Journal of the American Chemical Society, 2002 , vol. 124, # 14 p. 3508 - 3509
反应条件
bismuth(III) chloride; methyltrichloromonosilane in dichloromethane Ambient temperature;
参考文献
Montero, Jean-Louis; Winum, Jean-Yves; Leydet, Alain; Kamal, Mehrnaz; Pavia, Andre A.; Roque, Jean-Pierre
Carbohydrate Research, 1997 , vol. 297, # 2 p. 175 - 180
反应条件
hydrogenchloride; acetyl chloride T=-70°C;
参考文献
Korytnyk; Mills
Journal of the Chemical Society, 1959 , p. 636,644
反应条件
1: iodine; aluminium / dichloromethane / 4 h / 20 °C / Inert atmosphere 2: dichloromethane / 3 h / 0 - 20 °C / Inert atmosphere View Scheme
参考文献
Weng, Shiue-Shien; Li, Chia-Ling; Liao, Chun-Sheng; Chen, Ting-An; Huang, Chao-Cheih; Hung, Kuo-Tung
Journal of Carbohydrate Chemistry, 2010 , vol. 29, # 8-9 p. 429 - 440
反应条件
1: benzylamine / tetrahydrofuran / 16 h / 20 °C 2: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 3 h / 20 °C 3: boron trifluoride diethyl etherate / dichloromethane / 2 h / -20 °C 4: palladium on activated charcoal; sodium tetrahydroborate / dichloromethane; methanol / 0.25 h / 0 °C 5: sodium methylate; methanol / 16 h / 20 °C View Scheme
参考文献
Chemistry of Materials, , vol. 25, # 20 p. 4122 - 4128
反应条件
1: 90 percent / tin(IV) chloride / CH2Cl2 / 16 h / 20 °C 2: 1 N sodium methoxide / methanol / 16 h / 20 °C 3: 90.2 percent / 50percent sodium hydride / dimethylformamide; paraffin / 16 h / 20 °C 4: 77 percent / calcium carbonate, mercuric(II) chloride / acetonitrile; H2O / 5 h / Heating 5: thionyl chloride / dimethylformamide; 1,2-dichloro-ethane / 16 h / 20 °C View Scheme
参考文献
Sugawara, Fumio; Nakayama, Haruhiko; Strobel, Gary A.; Ogawa, Tomoya
Agricultural and Biological Chemistry, 1986 , vol. 50, # 9 p. 2251 - 2260
反应条件
1: SnCl4; 4A molecular sieves / CH2Cl2 / 4 h / 20 °C 2: MeONa / methanol / Heating View Scheme
参考文献
Droz, Anne Sophie; Neidlein, Ulf; Anderson, Sally; Seiler, Paul; Diederich, Francois
Helvetica Chimica Acta, 2001 , vol. 84, # 8 p. 2243 - 2289
反应条件
iodine in acetonitrile 96 h; Ambient temperatureother solvent, reaction time, reagents ratio; Product distribution;
参考文献
Kartha, K. P. Ravindranathan; Field, Robert A.
Journal of Carbohydrate Chemistry, 1998 , vol. 17, # 4-5 p. 693 - 702
反应条件
1: 79 percent / SnCl4 / CH2Cl2 2: 100 percent / NaOMe / methanol View Scheme
参考文献
Tran, Anh-Tuan; Burden, Richard; Racys, Daugirdas T.; Carmen Galan
Chemical Communications, 2011 , vol. 47, # 15 p. 4526 - 4528
反应条件
1: 79 percent / SnCl4 / CH2Cl2 2: 100 percent / NaOMe / methanol View Scheme
参考文献
Tran, Anh-Tuan; Burden, Richard; Racys, Daugirdas T.; Carmen Galan
Chemical Communications, 2011 , vol. 47, # 15 p. 4526 - 4528
