2-(2-硝基乙基)-[1,3]二氧戊烷合成路线 （共 5 条）
反应条件
Amberlite IR-900 (nitrite form) in benzene T=20°C; 36 h;
参考文献
Crumbie, Robyn L.; Nimitz, Jonathan S.; Mosher, Harry S.
Journal of Organic Chemistry, 1982 , vol. 47, # 21 p. 4040 - 4045
反应条件
toluene-4-sulfonic acid in benzene 3.5 h; Heating;
参考文献
Oehrlein, Reinhold; Schwab, Wilfried; Ehrler, Rudolf; Jaeger, Volker
Synthesis, 1986 , # 7 p. 535 - 538
反应条件
hydrogen; platinum(IV) oxide in ethanol P=2947.7 Torr;
参考文献
Crumbie, Robyn L.; Nimitz, Jonathan S.; Mosher, Harry S.
Journal of Organic Chemistry, 1982 , vol. 47, # 21 p. 4040 - 4045
反应条件
1: chromatographic alumina / 23 h / 20 °C
2: 82 percent / potassium dichromate, 30percent sulfuric acid / tetra-n-butylammonium hydrogen sulfate / CH2Cl2 / 2 h / -10 °C
View Scheme
参考文献
Rosini, Goffredo; Ballini, Roberto; Sorrenti, Pietro; Petrini, Marino
Synthesis, 1984 , # 7 p. 607 - 608
反应条件
1: 79 percent / Amberlist A 21 / 4 h
2: 71 percent / pyridinium chlorochromate, molecular sieves / CH2Cl2 / 36 h / Ambient temperature
View Scheme
参考文献
Rosini, Goffredo; Ballini, Roberto; Petrini, Marino; Sorrenti, Pietro
Tetrahedron, 1984 , vol. 40, # 19 p. 3809 - 3814
