alpha,alpha-二甲基苯乙酸合成路线 (共 89 条)
反应条件
1: diluted aqueous nitric acid / 200 - 350 °C 2: aqueous alkaline KMnO4 View Scheme
参考文献
Journal of the Chemical Society, , p. 2734,2740
反应条件
1: diethyl ether; potassium-sodium-alloy 2: carbon dioxide View Scheme
参考文献
Justus Liebigs Annalen der Chemie, , vol. 437, p. 254
反应条件
1: NaNH2 2: (hydrolysis) View Scheme
参考文献
Bulletin de la Societe Chimique de France, , p. 1115 - 1121
反应条件
aluminium trichloride
参考文献
Recueil des Travaux Chimiques des Pays-Bas, , vol. 37, p. 83
反应条件
water; anhydrous silver
参考文献
Tetrahedron, , vol. 46, # 19 p. 6753 - 6770
反应条件
Cs/Na/K alloy 1) NH3, -75 deg C, 2 h, 2) H2O; Yield given. Multistep reaction;
参考文献
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, , vol. 25, p. 185 - 186
反应条件
air; Ptlt;NPhNC(S)SCH3gt;2 in acetonitrile Ambient temperatureIrradiationrelative rate; Product distribution;
参考文献
Gazzetta Chimica Italiana, , vol. 116, # 6 p. 339 - 340
反应条件
Cs/Na/K alloy multistep reaction: 1.) THF, -75 deg C, 2 h, rate of cleavage relative to bibenzyl; Product distribution;
参考文献
Journal of the American Chemical Society, , vol. 105, # 20 p. 6290 - 6299
反应条件
1: isopropyl-benzene; C20H24O6(2-)*2K(1+) T=115°C; 1.5 h; 2: carbon dioxide
参考文献
Russian Journal of Organic Chemistry, , vol. 45, # 1 p. 26 - 29
反应条件
(i) nBuLi, heptane, (ii) /BRN= 1900390/; Multistep reaction;
参考文献
Journal of Organometallic Chemistry, , vol. 28, p. 153 - 158