alpha-环丙基苯乙烯合成路线 （共 11 条）
反应条件
(hydroxy(tosyloxy)iodo)benzene in methanol T=20°C; 0.333333 h;
参考文献
Justik, Michael W.; Koser, Gerald F.
Tetrahedron Letters, 2004 , vol. 45, # 32 p. 6159 - 6163
反应条件
T=40°C; Addition; Irradiation; Title compound not separated from byproducts;
参考文献
Ogawa, Akiya; Ogawa, Ikuko; Sonoda, Noboru
Journal of Organic Chemistry, 2000 , vol. 65, # 22 p. 7682 - 7685
反应条件
lithium aluminium tetrahydride; alpha,alpha-dimethylbenzyl hydroperoxide; oxygen 1) cumene, heating; Yield givenMultistep reaction;
参考文献
Journal fuer Praktische Chemie - Practical Applications and Applied Chemistry (Germany), , vol. 341, # 1 p. 52 - 58
反应条件
(i) aq. Hg(OAc)2, THF, (ii) NaBH4, aq. NaOH; Multistep reaction;
参考文献
Journal of Organometallic Chemistry, , vol. 156, p. 37 - 44
反应条件
potassium permanganate
参考文献
Zhurnal Obshchei Khimii, , vol. 20, p. 855,860; engl. Ausg. S. 891, 895
反应条件
oxygen in chlorobenzene T=95°C; 6.6 h; var. of temp., solvent, addition of cumene hydroperoxide, ΔEA; Product distributionThermodynamic dataKinetics;
参考文献
Journal fuer Praktische Chemie - Practical Applications and Applied Chemistry (Germany), , vol. 341, # 1 p. 52 - 58
反应条件
HMo(CO)3Cp* in toluene
T=60°C; other temperatures, other metal carbonyl hydrides, kinetic deuterium isotopic effects; 2-cyclopropylpropene instead of α-cyclopropylstyrene; Product distributionRate constantMechanism;
参考文献
Bullock, R. Morris; Rappoli, Brian J.; Samsel, Edward G.; Rheingold, Arnold L.
Journal of the Chemical Society, Chemical Communications, 1989 , # 4 p. 261 - 263
反应条件
in toluene
Kinetics; 22°C, yield of CH3CH(Ph)C3H5 and PhC(CH3)=CHCH2CH3 >90percent; NMR, IR;
参考文献
Morris Bullock; Samsel, Edward G.
Journal of the American Chemical Society, 1990 , vol. 112, # 19 p. 6886 - 6898
反应条件
in toluene
Kinetics; 22°C, yield of CH3CH(Ph)C3H5 and PhC(CH3)=CHCH2CH3 53percent; NMR, IR;
参考文献
Morris Bullock; Samsel, Edward G.
Journal of the American Chemical Society, 1990 , vol. 112, # 19 p. 6886 - 6898
反应条件
in benzene-d6
Kinetics; react. is carried out in a 5 mm NMR tube; CPS, then benzene and bibenzyl are added to the NMR tube contg. Hg, then HMn(CO)5 is added by vacuum transfer and the tube is sealed., react. for 3.5 h, 22°C, various product ratio for various conditions; react. is monitored by NMR;
参考文献
Bullock, R. Morris; Rappoli, Brian J.
Journal of Organometallic Chemistry, 1992 , vol. 429, # 3 p. 345 - 368
