8-甲基-1,4-二氧杂螺[4.5]癸-6-烯合成路线 （共 2 条）
反应条件
disodium hydrogenphosphate; sodium amalgam in methanol
0.5 h; Ambient temperature; Yield given. Yields of byproduct given;
参考文献
Paquette, Leo A.; Kinney, William A.
Tetrahedron Letters, 1982 , vol. 23, # 2 p. 131 - 134
反应条件
1: 87 percent / N-bromosuccinimide / dimethylsulfoxide; H2O / 10 °C
2: 80 percent / pyridine, chromium trioxide, celite / CH2Cl2 / 20 - 25 °C
3: 85 percent / tributyltinhydride, AIBN / benzene / 4 h / Heating
View Scheme
参考文献
Vankar, Yashwant D.; Chaudhuri, Narayan C.; Rao, C. Trinadha
Tetrahedron Letters, 1987 , vol. 28, # 5 p. 551 - 554
