(i) aq. KOH, benzene, (ii) I2, benzene; Multistep reaction;

water in 1,4-dioxane T=32.5°C; pH=6.49; 26.6667 h; aq. acetate buffer; KineticsThermodynamic data; Temperature;

water in 1,4-dioxane T=35°C; pH=6.5; 33.3333 h; aq. acetate buffer; Kinetics;

sodium perchlorate; sodium nitrite T=9.9 - 29.9°C; ΔH(excit.), -ΔS(excit.); various acids as catalysts (AcOH, ClCH2CO2H, Cl2CHCO2H, Cl3CO2H, HClO4); also primary kinetic isotope effect; Rate constantMechanismThermodynamic data;

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