2-甲基-2-(1-甲基丙基)丙烷-1,3-二醇合成路线 （共 10 条）
反应条件
1: Al(OiPr)3 / xylene / Heating 2: H2SO4 View Scheme
参考文献
Ferrari,G.; Casagrande,C.
Farmaco, Edizione Scientifica, 1963 , vol. 18, p. 780 - 792
反应条件
aluminum isopropoxide; toluene
参考文献
Ferrari,G.; Casagrande,C.
Farmaco, Edizione Scientifica, 1963 , vol. 18, p. 780 - 792
参考文献
Ferrari,G.; Casagrande,C.
Farmaco, Edizione Scientifica, 1963 , vol. 18, p. 780 - 792
反应条件
1: H2 / (Ph3P)3Rh(CO)H
2: KOH / ethanol
View Scheme
参考文献
Munro, David; Newman, Chris
Tetrahedron Letters, 2000 , vol. 41, # 9 p. 1483 - 1486
反应条件
1: H+ / Heating
2: H2 / (Ph3P)3Rh(CO)H
3: KOH / ethanol
View Scheme
参考文献
Munro, David; Newman, Chris
Tetrahedron Letters, 2000 , vol. 41, # 9 p. 1483 - 1486
反应条件
1: palladium on activated charcoal; hydrogen / 3.5 h / 85 °C / 7500.75 Torr / |Large scale
2: sodium methylate / methanol; toluene / 5 h / 0 - 20 °C / |Large scale
3: sodium hydroxide / water / 80 - 90 °C / pH 2
4: 80 - 90 °C
5: sodium hydroxide; water / 80 °C
View Scheme
参考文献
International Flavors and Fragrances Inc.; Gavalda, Juan Adell; Narula, Anubhav P.S.; Perez, Ana Maria Collado
Patent: US2014/81034 A1, 2014 ;
反应条件
1: sodium methylate / methanol; toluene / 5 h / 0 - 20 °C / |Large scale
2: sodium hydroxide / water / 80 - 90 °C / pH 2
3: 80 - 90 °C
4: sodium hydroxide; water / 80 °C
View Scheme
参考文献
International Flavors and Fragrances Inc.; Gavalda, Juan Adell; Narula, Anubhav P.S.; Perez, Ana Maria Collado
Patent: US2014/81034 A1, 2014 ;
反应条件
1: sodium hydroxide / water / 80 - 90 °C / pH 2
2: 80 - 90 °C
3: sodium hydroxide; water / 80 °C
View Scheme
参考文献
International Flavors and Fragrances Inc.; Gavalda, Juan Adell; Narula, Anubhav P.S.; Perez, Ana Maria Collado
Patent: US2014/81034 A1, 2014 ;
反应条件
lithium aluminium tetrahydride; diethyl ether
参考文献
Carter Prod. Inc.
Patent: US2878280 , 1955 ;
反应条件
1: ion-exchange resin <H+ form>
2: aq. Na2CO3
View Scheme
参考文献
Ferrari,G.; Casagrande,C.
Farmaco, Edizione Scientifica, 1963 , vol. 18, p. 780 - 792
