1,1,1,2-四氟乙烷合成路线 （共 120 条）
反应条件
1: 1,1,1-trifluoro-2-fluoroethane With zinc(II) chloride; lithium diisopropyl amide in tetrahydrofuran
T=15 - 20°C;
2: 4-bromo-1-iodobenzene With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
T=20°C; 18 h; Title compound not separated from byproducts;
参考文献
Raghavanpillai, Anilkumar; Burton, Donald J.
Journal of Organic Chemistry, 2004 , vol. 69, # 21 p. 7083 - 7091
反应条件
hydrogen; oxygen; fluorine in gaseous matrix
T=-63.1 - 89.9°C; P=200 Torr; Irradiationacivation energy data for intermediate rections; KineticsMechanismThermodynamic data;
参考文献
Maricq, M. Matti; Szente, Joseph J.; Hurley, Michael D.; Wallington, Timothy J.
Journal of Physical Chemistry, 1994 , vol. 98, # 36 p. 8962 - 8970
反应条件
hydrogen; oxygen; chlorine in gaseous matrix
T=22.9°C; P=700 Torr; Irradiation; Product distribution;
参考文献
Maricq, M. Matti; Szente, Joseph J.; Hurley, Michael D.; Wallington, Timothy J.
Journal of Physical Chemistry, 1994 , vol. 98, # 36 p. 8962 - 8970
反应条件
oxygen; chlorine
T=21.9°C; P=800 Torr; Irradiationalso in the presence of NO; Rate constant;
参考文献
Hasson; Moore; Smith
International Journal of Chemical Kinetics, 1998 , vol. 30, # 8 p. 541 - 554
反应条件
oxygen; chlorine
T=19.9°C; P=760 Torr; Irradiationfurther temp.; Product distributionMechanism;
参考文献
Rattigan, Oliver V.; Rowley, David M.; Wild, Oliver; Jones, Roderic L.; Cox, R. Anthony
Journal of the Chemical Society, Faraday Transactions, 1994 , vol. 90, # 13 p. 1819 - 1830
反应条件
air; water; chlorine
T=22.9°C; P=700 Torr; Irradiationother partial pressures of the components; reaction without water; Product distribution;
参考文献
Wallington, Timothy J.; Hurley, Michael D.; Schneider, William F.; Sehested, Jens; Nielsen, Ole John
Journal of Physical Chemistry, 1993 , vol. 97, # 29 p. 7606 - 7611
反应条件
oxygen; chlorine
T=21.9°C; P=750.06 Torr; 0.5 h; Irradiationvar. of temp., partial pressure, also addition of NO, Ea; Rate constantMechanismThermodynamic data;
参考文献
Bednarek; Ereil; Hoffmann; Kohlmann; Moers; Zellner
Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, 1996 , vol. 100, # 5 p. 528 - 539
反应条件
air; water; chlorine
T=22.9°C; P=700 Torr; Irradiationother partial pressures of the components; reaction without water; Product distribution;
参考文献
Wallington, Timothy J.; Hurley, Michael D.; Schneider, William F.; Sehested, Jens; Nielsen, Ole John
Journal of Physical Chemistry, 1993 , vol. 97, # 29 p. 7606 - 7611
反应条件
T=21.9°C; Rate constant;
参考文献
Bednarek; Ereil; Hoffmann; Kohlmann; Moers; Zellner
Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, 1996 , vol. 100, # 5 p. 528 - 539
反应条件
1: 1,1,1-trifluoro-2-fluoroethane With zinc(II) chloride; lithium diisopropyl amide in tetrahydrofuran
T=15 - 20°C;
2: ortho-iodofluorobenzene With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
T=65°C; 2 h;
参考文献
Raghavanpillai, Anilkumar; Burton, Donald J.
Journal of Organic Chemistry, 2004 , vol. 69, # 21 p. 7083 - 7091
