1,3-二甲基-1,1,3,3-四苯基二硅氧烷合成路线 （共 31 条）
反应条件
1: NaOH / toluene; methanol; isopropyl alcohol 2: CH3COOH / diethyl ether View Scheme
参考文献
Hyde et al.
Journal of the American Chemical Society, 1953 , vol. 75, p. 5615,5617
反应条件
1: methyl diphenyl silane With dirhodium tetraacetate; potassium carbonate in acetonitrile
Schlenk techniqueInert atmosphere;
2: carbon dioxide in acetonitrile
T=50°C; 24 h; Schlenk technique;
参考文献
Itagaki, Shintaro; Yamaguchi, Kazuya; Mizuno, Noritaka
Journal of Molecular Catalysis A: Chemical, 2013 , vol. 366, p. 347 - 352
反应条件
indium tribromide; oxygen in tetrahydrofuran
T=20°C; 2 h;
参考文献
Sridhar, Madabhushi; Ramanaiah, Beeram China; Narsaiah, Chinthala; Kumara Swamy, Mudam; Mahesh, Bellam; Kumar Reddy, Mallu Kishore
Tetrahedron Letters, 2009 , vol. 50, # 51 p. 7166 - 7168
反应条件
palladium on activated charcoal; hydrogen in THF-d8 (tetrahydrofuran-d8)
T=20°C; P=760.051 Torr; 1.5 h;
参考文献
Igarashi, Masayasu; Matsumoto, Tomohiro; Sato, Kazuhiko; Ando, Wataru; Shimada, Shigeru
Chemistry Letters, 2014 , vol. 43, # 4 p. 429 - 431
反应条件
trimethyl-oxonium tetrafluoroborate; potassium carbonate in acetonitrile
T=100°C; 1.5 h; Inert atmosphere;
参考文献
Jorapur, Yogesh R.; Shimada, Toyoshi
Synlett, 2012 , vol. 23, # 11 p. 1633 - 1638
反应条件
water; sodium hydrogencarbonate
参考文献
DOW CORNING CORPORATION; CHAO, Sung-Hsuen; HILBERER, Alain; KLEYER, Don, Lee; ZIMMERMAN, Kenneth; ZIOLKOWSKI, Nicolas
Patent: WO2014/71026 A1, 2014 ;
Location in patent: Paragraph 0040 ;
反应条件
trimethyl-oxonium tetrafluoroborate; potassium carbonate in acetonitrile
T=100°C; 1.5 h; Inert atmosphere;
参考文献
Jorapur, Yogesh R.; Shimada, Toyoshi
Synlett, 2012 , vol. 23, # 11 p. 1633 - 1638
反应条件
1 Au/TiO2; water in ethyl acetate
T=25°C; 1 h; Overall yield = 98 percent;
参考文献
Gryparis, Charis; Stratakis, Manolis
Chemical Communications (Cambridge, United Kingdom), 2012 , vol. 48, # 87 p. 10751 - 10753,3
反应条件
water; Petroleum ether
folgende Destillation;
参考文献
Kipping
Journal of the Chemical Society, 1927 , p. 105
反应条件
water in 1,4-dioxane
T=25°C; 0.25 h;
参考文献
Motokura, Ken; Kashiwame, Daiki; Miyaji, Akimitsu; Baba, Toshihide
Organic Letters, 2012 , vol. 14, # 10 p. 2642 - 2645
