3,3,4,4,5,5,5-七氟戊炔合成路线 （共 5 条）
反应条件
hydrogen fluoride
T=20°C; 24 h; Inert atmosphere;
参考文献
Bardin, Vadim V.; Adonin, Nicolay Yu.; Frohn, Hermann-Josef
Journal of Fluorine Chemistry, 2012 , vol. 135, p. 114 - 128
反应条件
zinc(II) chloride; zinc in N,N-dimethyl acetamide
T=100 - 120°C; 0.5 h;
参考文献
Petrov, V. A.; Belen'kii, G. G.; German, L. S.; Kurbakova, A. P.; Leites, L. A.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, # 1 p. 160 - 164
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 1 p. 170 - 174
参考文献
Hudlicky, M.
Journal of Fluorine Chemistry, 1981 , vol. 18, p. 383 - 406
反应条件
1: 66 percent / chlorine / neat (no solvent) / Irradiation
2: 1.) zinc; 2.) HCl / 1.) DMF, 100 deg C, 1 h
View Scheme
参考文献
Burton, Donald J.; Spawn, Terence D.
Journal of Fluorine Chemistry, 1988 , vol. 38, p. 119 - 124
反应条件
1: 82 percent / 4.33 h / 200 - 220 °C
2: 67.4 percent / Zn, Mg, conc.HCl / H2O / 3 h / 60 - 65 °C
View Scheme
参考文献
Hudlicky, M.
Journal of Fluorine Chemistry, 1981 , vol. 18, p. 383 - 406
