1.1: 92 percent / 4-dimethylaminopyridine / pyridine / 15 h 2.1: 80 percent / AgF / pyridine / 21 h / 20 °C 3.1: 78 percent / 3-chloroperoxybenzoic acid; NaHCO3 / CH2Cl2; H2O / 9 h / 20 °C 4.1: NaOMe / methanol / 24 h / 0 °C 4.2: Amberlite IR 120 (H+) / H2O / 4 h 5.1: 30 percent / aq. ammonia; H2 / Pd(OH)2/C / H2O / 96 h / 760 Torr View Scheme

1.1: NaOMe / methanol / 24 h / 0 °C 1.2: Amberlite IR 120 (H+) / H2O / 4 h 2.1: 30 percent / aq. ammonia; H2 / Pd(OH)2/C / H2O / 96 h / 760 Torr View Scheme

1.1: 78 percent / 3-chloroperoxybenzoic acid; NaHCO3 / CH2Cl2; H2O / 9 h / 20 °C 2.1: NaOMe / methanol / 24 h / 0 °C 2.2: Amberlite IR 120 (H+) / H2O / 4 h 3.1: 30 percent / aq. ammonia; H2 / Pd(OH)2/C / H2O / 96 h / 760 Torr View Scheme

1.1: 80 percent / AgF / pyridine / 21 h / 20 °C 2.1: 78 percent / 3-chloroperoxybenzoic acid; NaHCO3 / CH2Cl2; H2O / 9 h / 20 °C 3.1: NaOMe / methanol / 24 h / 0 °C 3.2: Amberlite IR 120 (H+) / H2O / 4 h 4.1: 30 percent / aq. ammonia; H2 / Pd(OH)2/C / H2O / 96 h / 760 Torr View Scheme

1: 92 mg / 2 h / 37 °C / immobilized rice α-glucosidase 2: H2 / 5percent Pd/C / ethanol; H2O; acetic acid / 16 h / 760 Torr View Scheme

cyclodextrin glycosyltransferase (EC 2.4.1.19); glucoamylase (EC 3.2.1.3); water 1.) H2O, 55 deg C, 48 h, 2.) 40 deg C, 4 h; Yield given. Multistep reaction;