2,2’-亚甲基双(4-(1,1-二甲基乙基)苯酚合成路线 （共 12 条）
反应条件
1: aq. HCl / 4 h / 100 °C 2: 65 percent / aq. CrO3, acetic anhydride / 1 h / 60 °C 3: 10percent aq. NaOH / methanol / 8 h / 50 °C View Scheme
参考文献
Ohba, Yoshihiro; Irie, Keisaku; Zhang, Fu Sheng; Sone, Tyo
Bulletin of the Chemical Society of Japan, 1993 , vol. 66, # 3 p. 828 - 835
反应条件
aluminium trichloride in toluene
T=0°C; 0.25 h;
参考文献
Sartori, Giovanni; Bigi, Franca; Maggi, Raimondo; Porta, Cecilia
Tetrahedron Letters, 1994 , vol. 35, # 38 p. 7073 - 7076
反应条件
1: 4-tert-butyl-phenol With ethylmagnesium bromide in diethyl ether
Heating;
2: formaldehyd in toluene
3 h; Heating;
参考文献
Rizzo, Simona; Sannicolo, Franco; Benincori, Tiziana; Schiavon, Gilberto; Zecchin, Sandro; Zotti, Gianni
Journal of Materials Chemistry, 2004 , vol. 14, # 12 p. 1804 - 1811
反应条件
toluene-4-sulfonic acid
Heating;
参考文献
Ohba, Yoshihiro; Ito, Kazuaki; Maeda, Hiroyuki; Ebara, Hiroaki; Takaki, Shin; Nagasawa, Tomomi
Bulletin of the Chemical Society of Japan, 1998 , vol. 71, # 10 p. 2393 - 2402
反应条件
potassium hydroxide; hydrogen; nickel in methanol
参考文献
Kaemmerer,H.; Haberer,K.
Monatshefte fuer Chemie, 1964 , vol. 95, p. 1589 - 1598
反应条件
1: aq. HCl / ethanol
2: H2, KOH / Raney-Ni / methanol
View Scheme
参考文献
Kaemmerer,H.; Haberer,K.
Monatshefte fuer Chemie, 1964 , vol. 95, p. 1589 - 1598
反应条件
1: aq. HCl / ethanol
2: H2, KOH / Raney-Ni / methanol
View Scheme
参考文献
Kaemmerer,H.; Haberer,K.
Monatshefte fuer Chemie, 1964 , vol. 95, p. 1589 - 1598
反应条件
1: 85 percent
2: 72 percent / AlCl3 / toluene / 0.25 h / 0 °C
View Scheme
参考文献
Sartori, Giovanni; Bigi, Franca; Maggi, Raimondo; Porta, Cecilia
Tetrahedron Letters, 1994 , vol. 35, # 38 p. 7073 - 7076
反应条件
potassium hydroxide in xylene
4 h; Heatingfurther bases (NaOH, CsOH, Mg(OH)2, Ca(OH)2, Ba(OH)2, LiOH, K2CO3); further solvents, effect of the heating rate; further substituted phenols; Product distributionMechanism;
参考文献
Gutsche,C.D.; Dhawan,B.; No,K.H.
Journal of the American Chemical Society, 1981 , vol. 103, p. 3782
反应条件
potassium hydroxide in xylene
4 h; Heatingfurther bases (NaOH, CsOH, Mg(OH)2, Ca(OH)2, Ba(OH)2, LiOH, K2CO3); further solvents, effect of the heating rate; further substituted phenols; Product distributionMechanism;
参考文献
Gutsche,C.D.; Dhawan,B.; No,K.H.
Journal of the American Chemical Society, 1981 , vol. 103, p. 3782
