[Pd{bis[2-(diphenylphosphino)phenyl] ether}Cl2]; triethylamine in water
T=20°C; 20 h; Inert atmosphere; optical yield given as percent dediastereoselective reaction;
参考文献
Moser, Ralph; Nishikata, Takashi; Lipshutz, Bruce H.
Organic Letters, 2010 , vol. 12, # 1 p. 28 - 31
1: dimethyl(phenyl)silyl chloride With lithium in tetrahydrofuran
T=0°C; 5 h; Inert atmosphere;
2: With zinc(II) chloride in tetrahydrofuran; diethyl ether
T=0°C;
3: (E)-(3-chloro-1-propenyl)benzene Further stages;
参考文献
Vyas, Devendra J.; Oestreich, Martin
Chemical Communications, 2010 , vol. 46, # 4 p. 568 - 570
1: dimethyl(phenyl)silyl chloride With lithium in tetrahydrofuran
T=0°C; 5 h; Inert atmosphere;
2: With zinc(II) chloride in tetrahydrofuran; diethyl ether
T=0°C;
3: 1-[(E)-3-bromo-1-propenyl]benzene Further stages;
参考文献
Vyas, Devendra J.; Oestreich, Martin
Chemical Communications, 2010 , vol. 46, # 4 p. 568 - 570
1: bis(dimethylphenylsilyl)zinc With copper(l) iodide in tetrahydrofuran
T=0°C; 0.333333 h;
2: rac-α-vinyl benzylacetate in tetrahydrofuran
T=0°C; Title compound not separated from byproducts;
参考文献
Oestreich, Martin; Auer, Gertrud
Advanced Synthesis and Catalysis, 2005 , vol. 347, # 5 p. 637 - 640
→
反应条件
1: bis(dimethylphenylsilyl)zinc With copper(l) iodide in tetrahydrofuran
T=0°C; 0.333333 h;
2: phenyl-carbamic acid 1-phenyl-allyl ester in tetrahydrofuran
T=0°C; Title compound not separated from byproducts;
参考文献
Oestreich, Martin; Auer, Gertrud
Advanced Synthesis and Catalysis, 2005 , vol. 347, # 5 p. 637 - 640
