2-氯-3-甲基-1-苯基-1-丁酮合成路线 （共 6 条）
反应条件
n-butyllithium; di-tert-butylnitroxide radical; diisopropylamine in tetrahydrofuran; hexane; dimethyl sulfoxide
T=10°C; 1 h; Irradiation;
参考文献
Russell, Glen A.; Mudryk, Boguslaw; Ros, Francisco; Jawdosiuk, Mikolaj
Tetrahedron, 1982 , vol. 38, # 8 p. 1059 - 1068
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide in tetrahydrofuran; hexane
T=-10 - 0°C; 1 h; Irradiation;
参考文献
Russell, Glen A.; Mudryk, Boguslaw; Jawdosiuk, Mikolaj
Journal of the American Chemical Society, 1981 , vol. 103, # 15 p. 4610 - 4611
反应条件
n-butyllithium; diisopropylamine in tetrahydrofuran; N,N,N',N',N'',N''-hexamethylphosphoric triamide; hexane
T=0 - 30°C; 1 h; Irradiation;
参考文献
Russell, Glen A.; Mudryk, Boguslaw; Ros, Francisco; Jawdosiuk, Mikolaj
Tetrahedron, 1982 , vol. 38, # 8 p. 1059 - 1068
反应条件
1: 48 percent / NaH / tetrahydrofuran; various solvent(s) / 0 °C
2: 15 percent
View Scheme
参考文献
Steiniger, Michael; Schaefer, Hans J.
Angewandte Chemie, 1982 , vol. 94, # 1 p. 75 - 76
反应条件
lithium diisopropyl amide
1.) THF, hexane, -30 deg C, 5 min, 2.) HMPA, irradiation, 0-30 deg C, 1 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Russel, Glen A.; Mudryk, Boguslaw; Jawdosiuk, Mikolaj; Wrobel, Zbigniew
Journal of Organic Chemistry, 1982 , vol. 47, # 10 p. 1879 - 1884
参考文献
Steiniger, Michael; Schaefer, Hans J.
Angewandte Chemie, 1982 , vol. 94, # 1 p. 75 - 76
