4-(反式-4-n-丙基环己基)苯乙酮合成路线 （共 16 条）
反应条件
1: aq. NaOH, Br2 / dioxane / 3 h / 35 - 40 °C 2: SOCl2 / 1 h / Heating 3: 63 percent / pyridine / dimethyl ether / overnight View Scheme
参考文献
Bezborodov, V. S.; Bubel', O. N.; Konovalov, V. A.; Ptashnikov, Yu. L.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 1479 - 1483
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 8 p. 1669 - 1674
反应条件
1: aq. NaOH, Br2 / dioxane / 3 h / 35 - 40 °C 2: SOCl2 / 1 h / Heating 3: 25percent aq. NH4OH 4: 56 percent / SOCl2, dimethylformamide / 1.5 h / Ambient temperature View Scheme
参考文献
Szczucinski; Dabrowski
Molecular crystals and liquid crystals, 1982 , vol. 88, # 1-4 p. 55 - 64
反应条件
sodium hydroxide; bromine in 1,4-dioxane T=35 - 40°C; 3 h; Yield given;
参考文献
Szczucinski; Dabrowski
Molecular crystals and liquid crystals, 1982 , vol. 88, # 1-4 p. 55 - 64
反应条件
1: AlCl3 / 45 °C
2: hydrazine hydrate / bis-(2-hydroxy-ethyl) ether / or in 1:1 mixture of triethanolamine and glycerol
3: AlCl3 / 1,2-dichloro-ethane / 0.5 h
View Scheme
参考文献
Bezborodov, V. S.; Bubel', O. N.; Konovalov, V. A.; Ptashnikov, Yu. L.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 1479 - 1483
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 8 p. 1669 - 1674
反应条件
1: AlCl3 / 45 °C
2: hydrazine hydrate / bis-(2-hydroxy-ethyl) ether / or in 1:1 mixture of triethanolamine and glycerol
3: AlCl3 / 1,2-dichloro-ethane / 0.5 h
View Scheme
参考文献
Bezborodov, V. S.; Bubel', O. N.; Konovalov, V. A.; Ptashnikov, Yu. L.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 1479 - 1483
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 8 p. 1669 - 1674
反应条件
1: AlCl3 / 45 °C
2: hydrazine hydrate / bis-(2-hydroxy-ethyl) ether / or in 1:1 mixture of triethanolamine and glycerol
3: AlCl3 / 1,2-dichloro-ethane / 0.5 h
View Scheme
参考文献
Bezborodov, V. S.; Bubel', O. N.; Konovalov, V. A.; Ptashnikov, Yu. L.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 1479 - 1483
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 8 p. 1669 - 1674
反应条件
1: 2.) 10percent aq. HCl / 1.) diethyl ether, 1 h, heating
2: p-toluenesulfonic acid / toluene / Heating
3: H2 / 10percent Pd/C / ethanol
4: AlCl3 / 1,2-dichloro-ethane / 0.5 h
View Scheme
参考文献
Bezborodov, V. S.; Bubel', O. N.; Konovalov, V. A.; Ptashnikov, Yu. L.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 1479 - 1483
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 8 p. 1669 - 1674
反应条件
1: H2 / 10percent Pd/C / ethanol
2: AlCl3 / 1,2-dichloro-ethane / 0.5 h
View Scheme
参考文献
Bezborodov, V. S.; Bubel', O. N.; Konovalov, V. A.; Ptashnikov, Yu. L.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 1479 - 1483
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 8 p. 1669 - 1674
反应条件
1: H2 / 10percent Pd/C / ethanol
2: AlCl3 / 1,2-dichloro-ethane / 0.5 h
View Scheme
参考文献
Bezborodov, V. S.; Bubel', O. N.; Konovalov, V. A.; Ptashnikov, Yu. L.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 1479 - 1483
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 8 p. 1669 - 1674
反应条件
1: p-toluenesulfonic acid / toluene / Heating
2: H2 / 10percent Pd/C / ethanol
3: AlCl3 / 1,2-dichloro-ethane / 0.5 h
View Scheme
参考文献
Bezborodov, V. S.; Bubel', O. N.; Konovalov, V. A.; Ptashnikov, Yu. L.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 1479 - 1483
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 8 p. 1669 - 1674
