2,2-二甲基丙基次基膦合成路线 （共 36 条）
反应条件
in tetrahydrofuran byproducts: CO; Irradiation (UV/VIS); UV-irradiation of W(CO)6 (4 h), addn. of RuCo-complex and t-BuCP (-30°C, stirring), slow warming to room temp., stirring (overnight); solvent removal, extn. (hexane), chromy. (SiO2);
参考文献
Bartsch, Rainer; Nixon, John F.; Sarjudeen, Nigel
Journal of Organometallic Chemistry, 1985 , vol. 294, p. 267 - 272
反应条件
in tetrahydrofuran Irradiation (UV/VIS); 16 h; solvent removal, dissoln. in hexane, chromy.;
参考文献
Bartsch, Rainer; Nixon, John F.; Sarjudeen, Nigel
Journal of Organometallic Chemistry, 1985 , vol. 294, p. 267 - 272
反应条件
in toluene sealed tube, 60°C, 16 h; solvent removal, dissoln. in hexane, chromy. (SiO2, hexane);
参考文献
Bartsch, Rainer; Nixon, John F.; Sarjudeen, Nigel
Journal of Organometallic Chemistry, 1985 , vol. 294, p. 267 - 272
反应条件
sodium hydroxide
T=160°C;
参考文献
Roesch, Wolfgang; Hees, Udo; Regitz, Manfred
Chemische Berichte, 1987 , vol. 120, p. 1645 - 1652
反应条件
1: With [Na(THF)x][PNb(N[Me3CCH2][3,5-Me2C6H3])3] in tetrahydrofuran
0.05 h;
2: in benzene-d6
T=80°C; 0.75 h;
参考文献
Figueroa, Joshua S.; Cummins, Christopher C.
Journal of the American Chemical Society, 2004 , vol. 126, # 43 p. 13916 - 13917
反应条件
sodium hydroxide in diethylene glycol dimethyl ether
T=20°C; 12 h;
参考文献
Becker, Gerd; Gresser, Gudrun; Uhl, Werner
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1981 , vol. 36, # 1 p. 16 - 19
反应条件
T=300°C; P=8E-05 Torr; Yield given;
参考文献
Regitz, Manfred; Binger, Paul
Angewandte Chemie, 1988 , vol. 100, # 11 p. 1541 - 1565
反应条件
in neat (no solvent)
byproducts: Ph2BOSiMe3, Ph2BP(SiMe3)2, Me3SiCl; room temperature; pptn. after 24 h, filtration, recrystn. (MeCN);
参考文献
Ionkin, A. S.; Chertanova, L. F.; Arbuzov, B. A.
Phosphorus, Sulfur and Silicon and the Related Elements, 1991 , vol. 55, # 1-4 p. 133 - 136
反应条件
in diethyl ether
T=0°C; 0.5 h;
参考文献
Roesch, Wolfgang; Facklam, Thomas; Regitz, Manfred
Tetrahedron, 1987 , vol. 43, # 14 p. 3247 - 3256
反应条件
in tetrahydrofuran
Ar-atmosphere; dropwise addn. of 1 equiv. phosphaalkyne to W-complex at -21°C (over 4 h), warming to 0°C; solvent removal (0.001 Torr, 0°C), sublimation off of phosphaalkyne complex (50°C, 0.001 Torr); product mixt. not sepd., detd. by NMR spectroscopy; elem. anal.;
参考文献
Scheer, Manfred; Kramkowski, Peter; Schuster, Kay
Organometallics, 1999 , vol. 18, # 15 p. 2874 - 2883
